Device capable of generating electric energy and simultaneously removing metal ions and method of device
A technology of metal ions and electric energy, applied in chemical instruments and methods, water/sewage treatment, water/sludge/sewage treatment, etc., can solve problems such as inability to treat wastewater, achieve mild conditions, simple operation, and achieve the effect of recycling
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Embodiment 1
[0045] The anolyte is potassium hydroxide solution of ethanol, the catholyte is the electrolytic solution of hexavalent chromium and sulfuric acid; the anode is carbon fiber cloth loaded with platinum catalyst, and the platinum load is 0.1-0.5mg Pt / cm 2 , the cathode is directly made of carbon fiber cloth; the cathode and anode liquids are completely separated, and the cathode chamber and the anode chamber are connected by an immobilized electrolyte made of gel / saturated potassium nitrate. The open circuit voltage is 0.6~2V, and the voltage can reach 0.05~1.5V under a certain external load. The removal rate of hexavalent chromium is over 90%.
Embodiment 2
[0047] The operation steps are the same as in Example 1, except that the two ends of the immobilized electrolyte are ion-exchange membranes, and a polymer containing ion-exchange groups is arranged in the middle of the ion-exchange membranes. Before use, the ion-exchange membranes need to be placed in hydrogen peroxide, Soak in one or more aqueous solutions of hydrochloric acid, sulfuric acid and sodium chloride at a temperature of 50-75°C for 3-5 hours, the anolyte is potassium hydroxide solution of ethanol, and the catholyte is a mixed aqueous solution of hexavalent chromium and sulfuric acid; The anode is a carbon fiber cloth loaded with a platinum catalyst, and the platinum loading is 0.1-0.5mg Pt / cm 2 , the cathode is directly made of carbon fiber cloth. The open circuit voltage is 0.6~2V, and the voltage can reach 0.05~1.5V under a certain external load. The removal rate of hexavalent chromium is over 90%.
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