Polyethylene material modified by rhodium complexes and preparation method and application thereof
A technology of rhodium complexes and polyethylene, which is applied in the field of polyethylene materials modified by rhodium complexes and its preparation and application, can solve problems such as bacterial invasion, patient infection, and lack of biocompatibility, so as to avoid infection and improve biocompatibility. Compatibility, the effect of excellent anti-bone cancer ability
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example 1
[0032] A polyethylene material, the surface of the polyethylene material is modified with a rhodium complex.
[0033] The structural formula of the rhodium complex is formula (I);
[0034]
[0035] The chemical name of the rhodium complex is: a chloro-m-thiazolylbenzaldehyde acetal 4-phenyl-3-thiosemicarbazide-pentamethylcyclopentadienyl rhodium (III), and the rhodium complex The molecular formula is: C 27 h 32 OSN 4 Rh, the relative molecular weight of the rhodium complex is: 563.543;
[0036] Physical and chemical properties: It is a red crystal, easily soluble in water and organic solvents, and its H NMR spectrum data is 1 HNMR (CDCl 3 solvent): δ=9.59(br,1H), 9.25(br,1H), 8.28(s,1H), 7.77(s,1H), 7.71(m,3H, J=7.6Hz), 7.62(t,1H ,J=7.6Hz),7.31(t,2H,J=7.9Hz),7.15(d,1H,J=7.2Hz),5.61(d,1H,J=6.0Hz),4.99(d,1H,J =6.0Hz), 4.75(d,1H,J=5.4Hz),4.51(d,1H,J=5.4Hz),3.68(s,3H),2.65(m,1H),2.56(m,1H,J = 6.9Hz), 2.39 (s, 3H), 1.36, 1.25 (2d, 6H, J = 6.7Hz) ppm.
[0037] The prepar...
example 2
[0051] A polyethylene material, the surface of the polyethylene material is modified with a rhodium complex.
[0052] The structural formula of the rhodium complex is formula (I);
[0053]
[0054] The chemical name of the rhodium complex is: a chloro-m-thiazolylbenzaldehyde acetal 4-phenyl-3-thiosemicarbazide-pentamethylcyclopentadienyl rhodium (III), and the rhodium complex The molecular formula is: C 27 h 32 OSN 4 Rh, the relative molecular weight of the rhodium complex is: 563.543.
[0055] The preparation method of described rhodium complex comprises the following steps:
[0056] Step 1. Dissolve 3-(2-thiazolyl)-benzaldehyde in absolute ethanol, add 4-phenyl-3-thiosemicarbazide, stir under reflux at 60°C, and react for 4 to 6 hours to obtain a slightly purple color solution, rotary evaporation to obtain the first concentrated product, adding ethanol and n-hexane, and standing to separate out white crystals to obtain m-thiazolylbenzaldehyde acetal 4-phenyl-3-thiose...
example 3
[0069] A polyethylene material, the surface of the polyethylene material is modified with a rhodium complex.
[0070] The structural formula of the rhodium complex is formula (I);
[0071]
[0072] The chemical name of the rhodium complex is: a chloro-m-thiazolylbenzaldehyde acetal 4-phenyl-3-thiosemicarbazide-pentamethylcyclopentadienyl rhodium (III), and the rhodium complex The molecular formula is: C 27 h 32 OSN 4 Rh, the relative molecular weight of the rhodium complex is: 563.543.
[0073] The preparation method of described rhodium complex comprises the following steps:
[0074] Step 1. Dissolve 3-(2-thiazolyl)-benzaldehyde in absolute ethanol, add 4-phenyl-3-thiosemicarbazide, stir under reflux at 70°C, and react for 6 hours to obtain a slightly purple solution. Rotary evaporation to obtain the first concentrate, adding ethanol and n-hexane, standing to separate out white crystals, to obtain m-thiazolylbenzaldehyde acetal 4-phenyl-3-thiosemicarbazide, its struct...
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