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Transition metal complex used as phosphor material, and preparation method and application thereof

A transition metal, phosphorescent material technology, applied in the direction of luminescent materials, platinum-based organic compounds, compounds containing elements of Group 8/9/10/18 of the periodic table, etc.

Inactive Publication Date: 2018-07-20
YANTAI XIANHUA OPTOELECTRONICS INST CORP LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the selection of ligands is still a hotspot and difficulty in the design and synthesis of phosphorescent materials.

Method used

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  • Transition metal complex used as phosphor material, and preparation method and application thereof
  • Transition metal complex used as phosphor material, and preparation method and application thereof
  • Transition metal complex used as phosphor material, and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] The synthesis of iridium complex Ir10, the reaction equation is as follows:

[0044] (1) Synthesis of chlorine-bridged dimers

[0045]

[0046] (2) Target synthesis

[0047]

Embodiment 2

[0049] The synthesis of iridium complex Ir8, reaction equation is as follows: (1) synthetic chlorine bridge dimer

[0050]

[0051] (2) Target synthesis

[0052]

Embodiment 3

[0054] The synthesis of iridium complex Ir11, reaction equation is as follows: (1) synthetic chlorine bridge dimer

[0055]

[0056] (2) Target synthesis

[0057]

[0058] Such as figure 1 As shown, the structure of an organic electroluminescent device (OLED) includes a glass substrate 1, an anode layer 2, a hole injection layer 3, a hole transport layer 4, a light emitting layer 5, an electron transport layer 6, and an electron injection layer sequentially stacked and combined. layer 7 and cathode layer 8. The iridium phosphorescent material prepared by the present invention is applied in the light-emitting layer of the OLED, and Table 1 shows the composition of each layer of the OLED in application examples 1-3.

[0059] Table 1

[0060]

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PUM

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Abstract

The invention belongs to the technical field of an organic optoelectronic material, and particularly relates to a transition metal complex used as a phosphor material, and a preparation method and application thereof. Through the matching of Z1, Z2 and Z3, the emission light wavelength of the material can be regulated in a large wavelength range; meanwhile, main ligands further and finely regulatethe wavelength of the emitting light through heteroatoms, thus realizing the important value on luminous materials with various wavelengths. The prepared complex has high luminous efficacy; the wavelength of the emission light is adjustable in a large range. The main ligands of the complex have the same framework structure. By changing the functional group positions, positions of the hetero atomson the main ligands and the types of the hetero atoms, the large-range regulation of the emitting light wavelength from the emitting light wavelength to dark red light can be realized. In addition, the preparation methods of luminous materials of different colors are basically identical; the operation is simple.

Description

technical field [0001] The invention belongs to the technical field of organic photoelectric materials, and in particular relates to a class of transition metal complexes used as phosphorescent materials, a preparation method and applications thereof. Background technique [0002] Organic electroluminescent device (OLED), as a new generation of display technology, overcomes the shortcomings of the first generation of CRT displays, such as bulky, bulky, and high power consumption, and also overcomes the shortcomings of LCD displays such as small viewing angle, slow response speed, unusable at low temperature, and The lack of self-luminescence, its biggest breakthrough lies in the mechanical toughness of the material, low-temperature process and sandwich device structure, not only can obtain better visual effects than conductive structure LCD, but also can be applied on any thin and light substrate, with very Attractive application prospects, great development potential. [0...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F15/00C09K11/06H01L51/54
CPCC09K11/06C07F15/0033C07F15/006C07F15/0086C09K2211/185H10K85/341H10K85/346H10K85/342
Inventor 陈跃丰佩川杨阳胡灵峰王培祥贾淑敏钱玉玲
Owner YANTAI XIANHUA OPTOELECTRONICS INST CORP LTD
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