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High-nickel eutectic high-entropy alloy powder for additive manufacturing and preparation method of high-nickel eutectic high-entropy alloy powder

A high-entropy alloy and additive manufacturing technology, which is applied in the coating process and coating of metal materials, can solve the problems of low plasticity and high-temperature strength, reduce surface oxidation, uniform and stable melting point, and reduce microscopic The effect of segregation

Pending Publication Date: 2020-08-11
ZHEJIANG ASIA GENERAL SOLDERING & BRAZING MATERIAL
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Problems solved by technology

[0004] In order to solve the problems of traditional high-entropy alloys or low-temperature strength or low plasticity and powder preparation process, the present invention provides a high-nickel eutectic high-entropy alloy powder for additive manufacturing and its preparation method

Method used

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[0024] The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments.

[0025] Taking the preparation of Al0.5CrFeCoNi2.1Si0.02B0.03 high nickel eutectic high entropy alloy powder as an example, the process flow is as follows figure 1 The specific operation process is as follows:

[0026] The weight of the metal element or intermediate alloy of each alloy element will be calculated according to the molar ratio of Al0.5CrFeCoNi2.1Si0.02B0.03 high-nickel eutectic high-entropy alloy, wherein the weight of aluminum is calculated according to the molar ratio of 0.51, and the weight of silicon and boron is calculated according to 0.021 Calculate the weight with the molar ratio of 0.032; put the weighed metal element ...

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Abstract

The invention relates to a high-nickel eutectic high-entropy alloy powder for additive manufacturing and a preparation method of the high-nickel eutectic high-entropy alloy powder. The high-nickel eutectic high-entropy alloy powder mainly comprises aluminum, iron, chromium, cobalt, nickel, silicon and boron elements, wherein the mole ratio of aluminum atoms is 0.5-1.5, the mole ratio of iron atomsis 1.0-1.5, the mole ratio of chromium atoms is 0.8-1.5, the mole ratio of cobalt atoms is 0.5-1.0, the mole ratio of nickel atoms is 1.0-2.5, the mole ratio of silicon atoms is 0-0.05, and the moleratio of boron atoms is 0-0.05. The preparation method of the powder includes the following steps that 1, a high-entropy master alloy is prepared by using a vacuum induction smelting furnace; and 2, the high-entropy alloy powder is prepared by using a crucible-free induction melting atomization furnace. The high-entropy alloy powder prepared by the preparation method is spherical or nearly spherical to form a eutectic structure, so that burning loss of low-melting-point elements and component segregation of the multi-element alloy are reduced, and rapid and precise manufacture and remanufacturing repair of high-temperature-resistant special parts can be effectively achieved. The high-nickel eutectic high-entropy alloy powder avoids the problems of low strength or poor plasticity of a traditional single-phase high-entropy alloy material.

Description

technical field [0001] The invention relates to the field of powder metallurgy, in particular to a high-nickel eutectic high-entropy alloy powder for additive manufacturing and a preparation method thereof. Background technique [0002] Traditional high-entropy alloys are prone to form simple face-centered cubic, simple body-centered cubic or hexagonal close-packed structures. Generally speaking, face-centered cubic structure HEA has good thermodynamic stability, super ductility and remarkable work hardening performance, but low strength; body-centered cubic or close-packed hexagonal structure HEA has high strength, But the ductility is poor. Eutectic high-entropy alloys have attracted extensive attention due to their high strength and ductility, which are suitable for various engineering applications. [0003] Additive manufacturing belongs to the rapid quenching forming process. On the one hand, it can avoid the shortcomings existing in the preparation of as-cast high-en...

Claims

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Application Information

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IPC IPC(8): C22C30/00C22C19/05C23C24/10
CPCC22C19/058C22C30/00C23C24/103
Inventor 金莹金霞刘平张腾辉翁子清史金光
Owner ZHEJIANG ASIA GENERAL SOLDERING & BRAZING MATERIAL
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