This invention discloses a method for multi-stage treatment of
copper-containing
wastewater based on
graphene oxide-assisted
electric field-driven process. The method utilizes a
graphene oxide-assisted N / O / S multi-coordinated
copper ion-imprinted cation exchange membrane as the selective separation interface, employs a membrane arrangement of
graphene oxide-assisted
copper ion-imprinted cation exchange membrane—anion exchange membrane—cation exchange membrane, and utilizes an
electric field for migration and release, with endogenous
carbonate as the circulating
crystallization medium in a
continuous treatment system. This
system can synergistically achieve the
decomposition and transformation of complexed copper, and the treatment of Cu... 2+ Selective migration and enrichment, polarity reversal release, and in-situ
crystallization recovery form "complex copper transformation-Cu". 2+ A closed-loop treatment pathway of "selective enrichment at the membrane interface – reverse release – internal
carbonate recycling and
crystallization recovery" is employed. This technology can reduce the consumption of external precipitants, lower the post-treatment pressure of copper-containing concentrate, and increase the value of copper
resource recovery, providing strong support for the in-depth treatment and
resource utilization of
wastewater containing complexed copper.