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Continuous heat shrinkable material with low smoke, low halogen and high pressure resistance and manufacturing method thereof

A manufacturing method and high-pressure-resistant technology, which is applied in the production process of low-smoke, low-halogen, high-pressure resistant continuous heat-shrinkable materials, can solve the problems of unsightly appearance of connecting joints and waste of materials, etc.

Inactive Publication Date: 2012-06-27
扬州辐照中心
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, heat-shrinkable materials in my country are mainly used in 35KV, 20 KV, 10KV, 1KV power transmission and distribution busbars and insulation protection for complete sets of electrical equipment. There are continuous types of 1KV heat-shrinkable sleeves, and 1m and 2m The fixed-length specifications are mainly used, and the appearance of the joints will be unsightly and waste materials due to cutting during use. The high-pressure pipe material is still a high-smoke and high-halogen product.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] According to embodiment 1 component is batched by weight:

[0028] Vinyl acetate copolymer (VA content 14-30) 40kg, polyethylene 10kg, hindered phenolic antioxidant 1kg, EPDM rubber 7kg, methyl vinyl silicone rubber 1kg, zinc stearate 1kg, epoxy 2kg of soybean oil, 18kg of nano-magnesium hydroxide, 5kg of antimony trioxide, 10kg of decabromodiphenylethane, 1.5kg of liquid triallyl isocyanurate, 3kg of red masterbatch, and 0.5kg of novel coupling agent.

[0029] Among them, the novel coupling agent is produced by Wuxi Henghui Chemical Co., Ltd.

[0030] A. Granulation:

[0031] First add vinyl acetate copolymer, anti-hindered phenolic antioxidant, EPDM rubber, methyl vinyl silicone rubber, zinc stearate, and epoxy soybean oil into the high-speed mixer for stirring, so that the materials are fully mixed The first granulation is completed through the twin-screw extruder air-cooled hot cutting granulation.

[0032] Then the first granulated material is mixed with nano-ma...

Embodiment 2

[0041] According to embodiment 2 components are batched by weight:

[0042] Vinyl acetate copolymer (VA content 14-30) 50kg, hindered phenolic antioxidant 0.8kg, EPDM rubber 5kg, methyl vinyl silicone rubber 1.2kg, zinc stearate 1kg, nano aluminum hydroxide 20 kg, antimony trioxide 5 kg, decabromodiphenylethane 10 kg, oxidized polyethylene wax 1.5 kg, liquid triallyl isocyanurate 1.5 kg, green color masterbatch 3 kg, novel coupling agent 1 kg.

[0043] A. Granulation:

[0044] First add vinyl acetate copolymer, hindered phenolic antioxidant, EPDM rubber, methyl vinyl silicone rubber, zinc stearate, and oxidized polyethylene wax into the high-speed mixer for stirring, so that the materials are fully mixed and then passed through The twin-screw extruder is air-cooled and hot-cut to granulate, and the first granulation is completed.

[0045] Then the pellets after the first granulation are mixed with nano-aluminum hydroxide, novel coupling agent, antimony trioxide, decabromodiphe...

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Abstract

The invention relates to a continuous heat shrinkable material with low smoke, low halogen and high pressure resistance and a manufacturing method thereof, and relates to the technical field of production processes of continuous heat shrinkable materials with low smoke, low halogen and high pressure resistance. The product consisting of 50 parts of polyolefin resin, 0.5-1 part of antioxidant, 4.5-9 parts of toughening agent, 28-48 parts of fire retardant, 1-4 parts of heat stabilizer, 1.5-3 parts of sensitizer, 3-5 parts of colored resin and 0.5-2 parts of novel coupling agent is formed by secondary pelleting, extruding, radiating and expanding; the continuous heat shrinkable material with low smoke, low halogen and high pressure resistance has an oxygen index of more than or equal to 28,a tensile strength of more than or equal 12MPa, and a breaking elongation rate of more than or equal to 500%; and the electrical performance can satisfy the corresponding high-pressure demand index, thus the material can be widely applied to the transformer substation bus insulating protection in a power supply system and the industries such as mining industry, chemical industry, petrifaction industry and the like.

Description

technical field [0001] The invention relates to the technical field of production technology of low-smoke, low-halogen high-pressure resistant continuous heat-shrinkable materials. Background technique [0002] Heat shrinkable material, also known as polymer shape memory material, is a kind of intelligent shape material combined with polymer material and radiation processing technology, that is, using the principle of "elastic memory" of polymer polymer, using rubber and plastic materials as the base material, after mixing , molding, cross-linking, heating, expansion, cooling and shaping of functional polymer materials. The macromolecular structure of polyethylene, polyolefin and other materials is usually a linear structure, which becomes a network structure after radiation cross-linking and has a "memory effect". When heated above the melting point, although the crystal grains melt, they do not appear in a fluid state, but have the elasticity of rubber. If the polyethylen...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/00C08L23/08C08L23/06B29B9/06B29C47/92B29C48/92
CPCB29C48/04B29C48/92B29C2948/92704B29C2948/92895
Inventor 曹宏杨宏玉陈秀兰刘芝平翟建青
Owner 扬州辐照中心
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