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Process for carrying out pretreatment on waste oil

A waste oil and pretreatment technology, which is applied in the direction of fat oil/fat refining and fat production, can solve the problems of unstable source, difficult unsaponifiable components, increasing the number and content of waste oil unsaponifiable components, etc., to improve oil Quality, reduction of coking, good raw material quality assurance effect

Inactive Publication Date: 2011-08-17
CHONGQING HAOTAI ENERGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

A large number of actual operation conditions show that this method will produce a large amount of coking, carbon deposition, and colloidal substances during the reaction process, which seriously affects the stable operation of production and the quality of subsequent products. An important reason for the above problems is that The waste oil used as raw material contains a considerable amount of peptizing impurities such as phospholipids, proteins, mucus, glycosyl diglycerides and unsaponifiable substances such as aliphatic polymers and complex metal salts. During the pretreatment process of waste oil, The degree of removal of these unsaponifiable components has a great influence on the subsequent esterification process of biodiesel production, the continuous operation of the refining process and product quality
[0004] Traditional oil refining processes include filtration, hydration, alkali refining, acid refining, and clay adsorption. These methods can effectively remove most of the mechanical impurities, water-soluble impurities and fat-soluble impurities in conventional animal and vegetable oils with relatively stable components, but for waste oils, due to their unstable sources, oil The species are not fixed, especially the high-temperature polymers and oxides contained in waste catering oil, which greatly increase the number and content of unsaponifiable components in waste oil, and it is difficult to effectively remove unsaponifiable components only by using the above-mentioned traditional methods

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] Embodiment 1: A waste oil pretreatment process of the present invention includes the following steps: adding waste oil into the pressure-resistant reactor of the reaction device, gradually turning on the steam under stirring and raising the temperature to 80°C, and then adding 40% of the total weight of waste oil Add the following decomposition agents in order: 2.5% concentrated sulfuric acid, 1.5% phosphoric acid, 1.5% sulfoxylyl fatty acid, the amount of the above decomposition agents is the weight percentage calculated based on the total weight of waste oil, continue Raise the temperature to 130°C, adjust the steam pressure and supply, and keep the temperature and pressure stable. After that, take a sample of the reaction material every hour to measure the acid value of the material. When the acid value of the reaction material rises to 160mgKOH / g in about 4 to 6 hours, turn off the steam. Stop heating; when the temperature drops to 95°C, turn off the stirring, and af...

Embodiment 2

[0017] Embodiment 2: A waste oil pretreatment process of the present invention includes the following steps: adding waste oil into the pressure-resistant reactor of the reaction device, gradually turning on the steam under stirring state and raising the temperature to 85°C, and then adding 30% of the total weight of waste oil Add the following decomposition agents in order: 1.5% concentrated sulfuric acid, 1.5% phosphoric acid, 1.5% sulfoxylyl fatty acid, the amount of the above decomposition agents is the weight percentage calculated based on the total weight of waste oil, continue Raise the temperature to 120°C to 140°C, adjust the steam pressure and supply rate, and keep the temperature and pressure stable. After that, the reaction material is sampled every hour to measure the acid value of the material. When the acid value of the reaction material rises to 140mgKOH / g in about 4 to 6 hours, Turn off the steam and stop heating; when the temperature drops to 95°C, turn off the...

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PUM

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Abstract

The invention discloses a process for carrying out pretreatment on waste oil, which comprises steps of waste oil dissolution, addition of a disintegrant for performing a reaction, sedimentation and impurity removal, electrolysis treatment and the like. The process has the advantages that in the process for carrying out pretreatment on the waste oil, the disintegrant with the specific components and content is added, so that most of fat-soluble colloidal impurities in the waste oil are transformed into water-soluble colloidal impurities; and under the action of electrolyte, colloidal particles adsorb water and are expanded, aggregated and settled to be discharged, so that various colloidal substances and unsaponifiable matter in the waste oil are effectively removed, the quality of the refined oil is well improved, good raw material quality guarantee is provided for the subsequent esterification and ester exchange process of biodiesel, and the degree of coking and carbon deposition in the esterification process is greatly reduced.

Description

technical field [0001] The invention relates to a waste oil pretreatment process. Background technique [0002] With the increasingly tense use of energy in the world, finding various new energy sources that can replace fossil energy sources has become one of the important research tasks of all countries in the world today. Biodiesel has attracted much attention in recent years because of its great advantages in power performance, environmental protection performance and safety performance, and has developed rapidly. [0003] At present, the production process of large-scale industrial production of biodiesel is mainly chemical method, which is the process of methyl esterification of oil and methanol under certain conditions of temperature, pressure and catalyst. A large number of actual operation conditions show that this method will produce a large amount of coking, carbon deposition, and colloidal substances during the reaction process, which seriously affects the stable...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C11B3/00C11B3/02C11B3/04
Inventor 陈恒顺严小建张宇金健沈建平申圣良
Owner CHONGQING HAOTAI ENERGY CO LTD