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A device and method for measuring the interdiffusion coefficient of a binary solution

A technology of mutual diffusion coefficient and binary solution, which is applied in measurement devices, diffusion analysis, instruments, etc., can solve the problem that the measurement accuracy needs to be further improved, and achieve the effect of improving the measurement accuracy and reducing the experimental intensity.

Active Publication Date: 2018-04-10
XI AN JIAOTONG UNIV
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Problems solved by technology

However, the existing laser interferometric interdiffusion coefficient measurement methods still have deficiencies in the diffusion body, filling process, holographic interferometric image processing, etc., and the measurement accuracy needs to be further improved

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  • A device and method for measuring the interdiffusion coefficient of a binary solution
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  • A device and method for measuring the interdiffusion coefficient of a binary solution

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Embodiment Construction

[0054] The present invention will be further described in detail below in conjunction with specific embodiments, which are to explain rather than limit the present invention.

[0055] The study of diffusion behavior in this paper mainly focuses on the mass transfer behavior caused by the concentration difference. The speed of the diffusion behavior is described by the diffusion coefficient. In this paper, the diffusion coefficient refers specifically to the mass diffusion caused by the concentration gradient.

[0056] See figure 1 , The device of the present invention suitable for measuring the mutual diffusion coefficient of binary solutions includes an interference light path, an experimental unit, and a detection and analysis unit. The experimental unit has a transparent experimental body 32 and a temperature and pressure measurement and control system. The experimental body 32 is filled with to be measured Liquid; the temperature and pressure measurement and control system is u...

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Abstract

A device and method for measuring the interdiffusion coefficient of a binary solution are provided. A good interface of different liquids can be formed by an experiment main body of the device, defects of diffusion main body preparation in the prior art are overcome, and the measurement precision is increased. According to the method, products of interdiffusion coefficients and time are determinedby fitting object light phase curves, and the interdiffusion coefficient is determined by utilizing a linear relation between the products and the diffusion time. The method can effectively avoid problems existing in present image processing methods, such as a problem that positions of extreme points and positions of solution interfaces before diffusion are difficult to determine accurately, anda problem that data processing processes are complex because the interdiffusion coefficient and the initial diffusion time point are obtained simultaneously by fitting a plurality of concentration curves. The interdiffusion coefficient measuring precision is significantly increased and experiment intensity is reduced.

Description

Technical field [0001] The invention belongs to the technical field of fluid thermophysical property measurement, and relates to a device and method suitable for measuring the mutual diffusion coefficient of a binary solution. Background technique [0002] Diffusion phenomenon is the thermal movement of molecules, which results in the movement of macroscopic mass under the action of a certain potential difference (such as concentration difference, temperature difference, pressure difference, etc.). The phenomenon of diffusion not only exists in daily life, but also exists in many fields such as energy, chemical industry, industrial safety, and medical treatment. Such as: the diffusion of electrolytes in the solution, the diffusion between the extractant and the target substance, the leakage and diffusion of toxic gases, the diffusion of protein molecules and trace elements in human blood, etc. The study of diffusion phenomena helps to make better use of diffusion to optimize the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N13/00
CPCG01N13/00G01N2013/003
Inventor 张颖何茂刚刘向阳张诗郑宇
Owner XI AN JIAOTONG UNIV
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