Composite function resin as well as preparation method and application thereof

A composite function and resin technology, applied in the field of resin, can solve problems such as poor anti-interference ability, and achieve the effects of moderate fluid resistance, high bactericidal activity, and good sedimentation

Active Publication Date: 2018-07-27
NANJING UNIV +1
View PDF7 Cites 6 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] Aiming at the problem that the existing resin has poor anti-interference ability and poor ability to remove dissolved organic matter in water, disinfection by-product precursors, anions such as nitrate, sulfate, phosphate and arsenate while sterilizing, the present invention provides a A composite functional resin, the composite functional resin of the present invention has the ability to efficiently remove soluble organic matter in water, the precursor of disinfection by-products, anions such as nitrate, sulfate, phosphate and arsenate, and has high-efficiency sterilization. Advantages of strong interference ability

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Composite function resin as well as preparation method and application thereof
  • Composite function resin as well as preparation method and application thereof
  • Composite function resin as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0101] control group

[0102] Prepare 500g of water phase: weigh 2.5g of hydroxyethyl cellulose, 25g of sodium sulfate, and the rest as water;

[0103] Add 500 g of the water phase into a 2L three-necked flask, and control the stirring speed at 300 rpm. Weigh 60g of the first monomer, in the present embodiment, the first monomer is glycidyl methacrylate, 60g glycidyl methacrylate (GMA), 10g divinylbenzene (DVB), 0.6g azobis Add isobutyl ester, 1.8g benzoyl peroxide, and 30g cyclohexanol into a three-necked flask and heat up to 60°C for 8 hours, then heat up to 90°C for 4 hours; cool to room temperature and collect white or off-white acrylic acid Resin balls are extracted, washed and dried, and acrylic resin is the first resin.

[0104]Synthesize and sort acrylic resin (average particle diameter 500um), weigh the first amine salt 80g, in the present embodiment, the first amine salt is dodecyldimethylamine hydrochloride, the first resin of 20g and 80g ten Dialkyldimethylamine...

Embodiment 2

[0111] Prepare 500g of water phase: weigh 2.5g of hydroxyethyl cellulose, 25g of sodium sulfate, and the rest as water;

[0112] Add 500 g of the water phase into a 2L three-necked flask, and control the stirring speed at 300 rpm. Weigh 60g of the first monomer, in the present embodiment, the first monomer is glycidyl methacrylate, 60g glycidyl methacrylate (GMA), 10g divinylbenzene (DVB), 0.6g azobis Add isobutyl ester, 1.8g benzoyl peroxide, and 30g cyclohexanol into a three-necked flask and heat up to 60°C for 8 hours, then heat up to 90°C for 4 hours; cool to room temperature and collect white or off-white resin Balls are extracted, washed and then dried to obtain the first resin.

[0113] Synthesize and sort the first resin (average particle diameter 500um), take by weighing the first amine salt 80g, in the present embodiment, the first amine salt is dodecyldimethylamine hydrochloride, the first resin of 20g and 80g Dodecyldimethylamine hydrochloride was placed in a 250...

Embodiment 3

[0120] The first monomer of this embodiment is selected from formula (401), when R 0 for H, R 1 for -CH 3 , when t=1, the first monomer structure is formula (401-1),

[0121]

[0122] The specific implementation is as follows:

[0123] Prepare 500g of water phase: weigh 2.5g of methylcellulose, 5g of sodium dodecylbenzenesulfonate, 50g of sodium sulfate, and the rest as water;

[0124] Add 500 g of the water phase into a 2L three-necked flask, and control the stirring speed at 400 rpm. The first monomer represented by 40g formula (401-1), 20g methyl acrylate (MA), 20g styrene, 5g ethylene glycol dimethacrylate, 10g trimethylolpropane trimethacrylate, Add 1.0g of azobisisobutyl ester, 10g of 200# solvent oil, and 10g of n-butanol into a three-necked flask and heat up to 50°C for 12 hours, then heat up to 80°C for 4 hours; cool to room temperature and collect white or Off-white resin balls are extracted, washed and dried to obtain the first resin.

[0125] Synthesize an...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
Login to view more

Abstract

The invention discloses composite function resin, and belongs to the field of resin. The composite functional resin has a basic structure shown as a formula (I) and / or a formula (II), wherein the AX is a quaternary ammonium group. By aiming at the problems that the existing resin has poor anti-interference capability during sterilization, and the capability of removing soluble organic matters in the water and sterilizing byproduct precursors and poor ability of negative ions such as nitrate radical, sulfate radical, phosphate radical and arsenate radical, the invention provides the composite function resin. The composite function resin simultaneously has the capability of effectively eliminating soluble organic matter in the water and sterilizing the byproduct precursors and negative ionssuch as nitrate radical, sulfate radical, phosphate radical and arsenate radical, and has the advantages of efficient sterilization capability and anti-interference capability. The invention providesa preparation method of the composite function resin, application of the composite function resin to sterilization, and application of the composite function resin to water treatment. The formulas areshown in the description.

Description

technical field [0001] The invention belongs to the field of resins, and in particular relates to a composite functional resin as well as its preparation method and application. Background technique [0002] The disinfection process is the most important way to kill pathogenic microorganisms and ensure the safety of drinking water, mainly including chemical methods such as chlorine gas, chloramine, sodium hypochlorite, chlorine dioxide, ozone, compound disinfection, and physical methods such as ultraviolet radiation. However, during the disinfection process, chemical disinfectants will react with natural organic matter, artificially synthesized organic pollutants, bromide, iodide, etc. in water to generate a variety of disinfection by-products, such as trihalomethanes, haloacetic acids, haloacetonitriles, and nitrosamines. Wait. Many disinfection by-products are genotoxic and carcinogenic, which seriously threaten the safety of drinking water. UV disinfection can also caus...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08F8/44C08F220/32C08F212/36C08F220/14C08F212/08C08F222/14C08F220/18C08F212/14C08F224/00C08F226/06A01N33/12A01P1/00C02F1/50C02F1/42C02F1/58C02F101/10C02F101/16C02F101/30
CPCA01N33/12C02F1/42C02F1/50C02F1/58C08F8/44C08F212/14C08F220/32C08F224/00C08F226/06C02F2101/30C02F2101/163C02F2101/101C02F2101/103C02F2101/105C02F2001/422C08F220/325C08F212/36C08F222/102C08F220/14C08F212/08C08F222/103C08F220/1804C02F1/288C02F2303/04A01N25/10A01P1/00C02F2001/425
Inventor 施鹏张怀成李爱民常芳瑜周庆双陈冬李启蒙潘旸
Owner NANJING UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap