Fusion formable sodium free glass
a sodium free glass and fusion technology, applied in the field of sodium free glasses, can solve the problemsaffecting the quality of the glass body, and affecting the quality of the glass body, and achieving the effects of reducing the life of the platinum system
Inactive Publication Date: 2016-06-09
CORSAM TECH
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Benefits of technology
[0012]A compositional range of fusion-formable, high strain point sodium free, silicate, aluminosilicate and boroaluminosilicate glasses useful, for example, for thin-film photovoltaic applications are described herein. More specifically, these glasses are advantageous materials to be used in copper indium gallium diselenide (CIGS) photovoltaic modules where the sodium required to optimize cell efficiency is not to be derived from the substrate glass but instead from a separate deposited layer consisting of a sodium containing material such as NaF. Current CIGS module substrates are typically made from soda-lime glass sheet that has been manufactured by the float process. However, use of higher strain point glass substrates can enable higher temperature CIGS processing, which is expected to translate into desirable improvements in cell efficiency. Moreover, it may be that the smoother surface of fusion-formed glass sheets yields additional benefits, such as improved film adhesion, etc.
Problems solved by technology
These glasses share in common 200p temperatures in excess of 1600° C., which can translate to accelerated tank and electrode corrosion, greater challenges for fining due to still more elevated finer temperatures, and / or reduced platinum system life time, particularly around the finer.
Many have temperatures at 3000 poise in excess of about 1300° C., and since this is a typical viscosity for an optical stirrer, the high temperatures at this viscosity can translate to excessive stirrer wear and elevated levels of platinum defects in the body of the glass.
Many of the above described glasses have delivery temperatures in excess of 1200° C., and this can contribute to creep of isopipe refractory materials, particularly for large sheet sizes.
These attributes combine so as to limit flow (because of slow melt rates), to accelerate asset deterioration, to force rebuilds on timescales much shorter than product lifetimes, to force unacceptable (arsenic), expensive (capsule) or unwieldy (vacuum fining) solutions to defect elimination, and thus contribute in significant ways to the cost of manufacturing glass.
In applications in which rather thick, comparatively low-cost glass with less extreme properties is required, these glasses are not only overkill, but prohibitively expensive to manufacture.
In applications that are cost sensitive, such as large-area photovoltaic panels and OLED lighting, this cost differential is so large as to make the price point of LCD-type glasses unacceptable.
Method used
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examples
[0160]The following is an example of how to fabricate a sample of an exemplary glass, according to one embodiment of the invention, as shown in Table 1. This composition corresponds to composition number 22 shown in Table 5.
TABLE 1oxidemol %SiO264.93Al2O30MgO17.5CaO0SrO0B2O30K2O17.5SnO20.10BaO0
In some embodiments, the total does not add up to 100%, since certain tramp elements are present at non-negligible concentrations.
[0161]Batch materials, as shown in Table 2 were weighed and added to a 4 liter plastic container:
TABLE 2Batch ComponentssandMagnesiaPotassium carbonate10% SnO2 and 90% sand
[0162]It should be appreciated that in the batch, limestone, depending on the source can contain tramp elements and / or vary amounts of one or more oxides, for example, Mg0 and / or BaO. The sand is advantageously beneficiated so that at least 80% by mass passes 60 mesh, for example 80 mesh, for example 100 mesh. The SnO2 added, in this example, was pre-mixed with sand at a level of 10% by weight so ...
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Abstract
A compositional range of fusion-formable, high strain point sodium free, silicate, aluminosilicate and boroaluminosilicate glasses are described herein. The glasses can be used as substrates for photovoltaic devices, for example, thin film photovoltaic devices such as CIGS photovoltaic devices. These glasses can be characterized as having strain points ≧540° C., thermal expansion coefficient of from 6.5 to 10.5 ppm / ° C., as well as liquidus viscosities in excess of 50,000 poise. As such they are ideally suited for being formed into sheet by the fusion process.
Description
[0001]This application claims the benefit of priority to U.S. Provisional Application No. 61 / 182404 filed on May 29, 2009, and U.S. patent application Ser. No. 12 / 788,763 filed on May 27, 2010.BACKGROUND[0002]1. Field[0003]Embodiments relate generally to sodium free glasses and more particularly to fusion formable sodium free glasses which may be useful in photochromic, electrochromic, Organic Light Emitting Diode (OLED) lighting, or photovoltaic applications, for example, thin film photovoltaics.[0004]2. Technical Background[0005]The fusion forming process typically produces flat glass with optimal surface and geometric characteristics useful for many electronics applications, for instance, substrates used in electronics applications, for example, display glass for LCD televisions.[0006]Over the last 10 years, Corning fusion glass products include 1737F™, 1737G™, Eagle2000F™, EagleXG™, Jade™, and Codes 1317 and 2317 (Gorilla Glass™). Efficient melting is generally believed to occur...
Claims
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IPC IPC(8): H01L31/048C03C3/091H01L31/032C03C3/089H01L31/0296C03C3/064C03C3/078
CPCH01L31/048C03C3/064C03C3/091H01L31/0322C03C3/089H01L31/0296C03C3/078H01L31/02366Y02E10/541Y02P70/50C03C3/076
InventorAITKEN, BRUCE GARDINERDICKINSON, JAMES EDWARDKICZENSKI, TIMOTHY J.PIERSON-STULL, MICHELLE DIANE
OwnerCORSAM TECH