The invention discloses a method for removing and comprehensively recycling
thiocyanate radicals in high-concentration
cyanide-containing
wastewater acidizing fluid, and belongs to the technical field of
metal refining. The method comprises the following steps: carrying out
solid-liquid separation on high-concentration
cyanide-containing
wastewater acidizing fluid, adding excessive
iron powder into filtrate, firstly introducing a low-temperature soluble
zinc salt weak acid solution into overflowing
mixed gas to fully absorb H2S and HCN gas in the
mixed gas to generate ZnS and Zn (CN) 2 turbid liquid, and then introducing a
sodium hydroxide strong alkaline solution to further absorb the ZnS and Zn (CN) 2 turbid liquid to ensure that H2S and HCN gas which are not completely absorbed does not overflow. Adding concentrated
sulfuric acid into the ZnS and Zn (CN) 2 turbid liquid, stirring for reaction, absorbing overflowing HCN gas by using alkali liquor, and filtering the turbid liquid after reaction to obtain ZnS filter residues and Zn < 2 + > filtrate; and filtering the acidizing fluid which fully reacts with the
iron powder, recycling the residual
iron powder, adjusting the pH value of the filtrate to be more than 11, filtering out the precipitate of iron
hydroxide, and returning to the
cyanogen-containing production water
system. The invention realizes the
recovery of CN <-> in SCN <-> and realizes the absorption and separation of H2S and HCN gas.