Impact-resistant polystyrene composition and its preparation method

A technology of impact-resistant polystyrene and composition, applied in the field of ultrafine powder rubber toughened polystyrene resin and its preparation, can solve the problems of unsatisfactory mechanical properties of blends, difficult dispersion state control, and harsh polymerization conditions and other problems, to achieve the effect of saving manpower and material resources, improving the dispersion state, and improving compatibility

Active Publication Date: 2009-05-27
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, it has been found that the use of small particle size, especially nano-scale rubber particles to toughen polystyrene resin can achieve better results. Most of them are based on the blending of nanoparticles and polystyrene, such as the patent publication number CN1556139 The blending of polystyrene and nano-sized polyamide-6 particles can properly improve the impact strength and fracture strength of the material, but it is difficult to control the dispersion state of the toughening particles in the polystyrene matrix due to the blending method. Effective control, the compatibility between the rubber particles and the polystyrene matrix is ​​poor, therefore, the mechanical properties of the obtained blends are not satisfactory
[0005] The traditional bulk polymerization method is mostly based on dissolving rubber in styrene to carry out graft polymerization. For example, patent CN1254722A discloses a rubber-containing styrene resin and its preparation method. It needs to ensure that styrene monomer and butadiene rubber The grafting ratio is not less than 1 and the particle size of butadiene rubber in polystyrene is controlled. The polymerization conditions are harsh and the process is relatively complicated.

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  • Impact-resistant polystyrene composition and its preparation method

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Embodiment Construction

[0026] The present invention is further described below through examples, to deepen the understanding of the present invention. The embodiment given below is to illustrate better but not to limit the present invention

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Abstract

The invention provides a novle impact polystyrene compound, which is prepared through polymerization by using phenylethene containing small grain- size powder. Said small grain- size powder is cross-linking powder rubber with its grain size being 20- 500 nm, the gel content is no less than 60wt%, and swelling index is no more than 15. The compatability between rubber particle and polyphenylacetylene is increased, and the dispersing condition of rubber particle in polyphenylacetylene is improved. So the flexibility of polyphenylacetylene compound is dramatically improved even the rubber particle content is very low, and the strength, rigidity and other mechanical performance are still maintained.

Description

technical field [0001] The invention relates to an impact-resistant polystyrene composition and a preparation method thereof, more specifically, the invention relates to an ultrafine powder rubber toughened polystyrene resin and a preparation method thereof. Background technique [0002] Polystyrene (PS) has a wide range of applications in various fields of industry and civil use because of its abundant raw materials, cheap price, easy molding process, low hygroscopicity and good transparency. It is a general-purpose plastic with a large amount of consumption. However, the intrinsic structure of polystyrene resin determines its lack of mechanical properties, such as insufficient strength, poor toughness, etc., especially brittle behavior due to its molecular chain internal structure. This largely limits its scope of application. [0003] In order to improve the toughness of polystyrene, the method of polymerization or blending is often used to incorporate toughening compone...

Claims

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Application Information

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Patent Type & AuthorityPatents(China)
IPC IPC(8): C08L25/06C08L7/00C08L9/00
Inventor王洪涛史新波斯维周俊领高克京乔金梁
OwnerCHINA PETROLEUM & CHEM CORP