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Styrene-butadiene latex composite modified asphalt and preparation method thereof

A technology of composite modified asphalt and styrene-butadiene latex, which is applied in building components, building insulation materials, buildings, etc., can solve the problems of small improvement in high temperature resistance, poor long-term storage stability, and unsatisfactory high-temperature performance, and achieve the goal of improving cohesion Effect

Active Publication Date: 2014-01-15
CHINA PETROLEUM & CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The addition of these polymer materials greatly improves the temperature sensitivity of asphalt materials and broadens the application temperature range of asphalt materials. However, resin asphalt modifiers such as PE can only improve the high temperature resistance of asphalt and require high shear. Grinding equipment can make it uniformly dispersed. Modified asphalt has poor stability, is easy to delaminate, and has high manufacturing costs. Although SBS thermoplastic elastomers can improve the high and low temperature performance of asphalt at the same time, high-shear grinding equipment is required, and the manufacturing cost is high. Inconvenient; rubber-based asphalt modifiers such as SBR have good low-temperature cracking resistance, and the time delay at 5°C is several times higher than that of ordinary asphalt, but the softening point of asphalt is not greatly improved, and the effect of improving high temperature resistance is small; such as the United States Patent US5002987 reports the performance of SBR modified asphalt, but SBR mainly improves the low temperature performance of asphalt, and the improvement of high temperature performance is not ideal, and the long-term storage stability is poor
Chinese patent CN1287133 discloses the method of using SBR and SBS composite modified asphalt, but because SBS is used as the modifier, colloid mill equipment is required, and the production process is relatively complicated. At the same time, the addition of sulfur will produce toxic hydrogen sulfide in the production process Gas, pollute the environment, and from the results of the segregation test, it can be seen that, except that the addition of SBR is 1.50%, the addition of SBS is 2.00% and the addition of SBR is 3.00%, and the separation degree is 0°C when the addition of SBS is 0.50%. , there is a certain degree of separation in the composite modified asphalt in the remaining examples, indicating that the storage stability of the composite modified asphalt prepared by this method is not good

Method used

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  • Styrene-butadiene latex composite modified asphalt and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0018] Will 400g heavy traffic volume 90 # The road asphalt is heated to 170°C, and then 40g of SBR (equivalent to 181.82g of SBR emulsion, grade of 1500, containing 22% SBR solid glue) is slowly added, and at the same time, the stirring equipment is started to stir slowly, and the heating is continued to remove the water in the SBR emulsion. After the water is removed, the temperature of the asphalt is slowly increased to 195℃, and 4g of MAC asphalt modifier is added. The particle size of the selected MAC asphalt modifier is below 0.6mm and the water content is 0.4%-1.2 %, the bulk density is 0.57-0.67g / cm 3 Between (the same below). Stir for 0.6h at a stirring speed of 550r / min until the modifier is uniformly dissolved, and then determine the performance of the modified asphalt. See Table 1.

Embodiment 2

[0020] Will 400g heavy traffic volume 70 # The road asphalt is heated to 170°C, and then 24g of SBR (equivalent to 109.09g of SBR emulsion, grade 1500, containing 22% SBR solid glue) is slowly added, and at the same time, the mixing equipment is started to stir slowly, and the heating is continued to remove the water in the SBR emulsion. After the water is removed, the temperature of the asphalt is slowly increased to 195°C, 8g of MAC asphalt modifier is added, and stirred at a stirring speed of 550r / min for 0.6h until the modifier is uniformly dissolved, and the performance of the modified asphalt is measured. See Table 1.

Embodiment 3

[0022] Will 400g heavy traffic volume 70 # The road asphalt is heated to 170°C, and then 20g of SBR (equivalent to 90.91g of SBR emulsion, grade 1500, containing 22% SBR solid glue) is slowly added, and at the same time, the mixing equipment is started to stir slowly, and the heating is continued to remove the water in the SBR emulsion. After the water is removed, the temperature of the asphalt is slowly increased to 195°C, 12g of MAC asphalt modifier is added, and stirred at a stirring speed of 550r / min for 0.6h until the modifier is uniformly dissolved, and the modified asphalt performance is measured. See Table 1.

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Abstract

The invention relates to the field of asphalt modification, and particularly relates to styrene-butadiene latex composite modified asphalt and a preparation method thereof. The preparation method comprises the following steps of: heating road asphalt till the road asphalt completely flows; then adding styrene-butadiene latex and an MAC (Media Access Control) asphalt modifying agent to the road asphalt, starting stirring till the MAC asphalt modifying agent is uniformly melted. The styrene-butadiene latex composite modified asphalt prepared through the method has excellent high-low temperature resistant comprehensive property, and can not only be applied to a high-temperature area, but also be applied to a cold area. Besides, the preparation method of the composite modified asphalt can complete the mixed reaction process by only adopting common stirring equipment without adopting high-shear grinding equipment, thus the preparation method has the advantages of simple process, small investment, low energy consumption and site blending, and is convenient to operate and apply.

Description

Technical field [0001] The field of asphalt modification of the present invention specifically relates to a styrene-butadiene latex composite modified asphalt and a preparation method thereof. Background technique [0002] As the main binding material in road engineering, asphalt has been widely used. However, due to the inherent shortcomings of asphalt materials are hot, cold, brittle, and strong temperature sensitivity, the asphalt pavement is prone to crowding and oiling in the high temperature in summer, and it is easy to cause cracking and other problems at low temperatures in winter, which affects the comfort and use of the road. life. Especially with the development of economy, the traffic volume, driving speed and traffic load are increasing day by day, which puts forward higher requirements on the performance and life of high-grade highways. The contradiction that asphalt materials cannot meet the requirements of use has become increasingly prominent. In order to furt...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L95/00C08L9/06C08K5/00C04B26/26
Inventor 贾丽凤高淑美马鹏程许金山刘爱华
Owner CHINA PETROLEUM & CHEM CORP
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