Anti-swelling shrinking agent
A technology of anti-expansion agent and ethylenediamine, which is applied in the field of clay anti-expansion, can solve the problems of clay expansion, no swelling function of expanded clay, poor anti-expansion effect of anti-expansion agent, etc., and achieve anti-hydration Strong action, good clay stabilization, good anti-swelling and shrinking-swelling effects
Active Publication Date: 2015-12-16
XIAN AODE PETROCHEM ENG TECH CO LTD
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- Abstract
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- Application Information
AI Technical Summary
Problems solved by technology
[0006] The purpose of the present invention is to provide an anti-swelling and shrinking agent, which is used to solve the problem of clay swelling caused by oil field development, and solves the problem that the existing anti-swelling agent has poor anti-swelling effect and does not have the function of shrinking and swelling the expanded clay.
Method used
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Embodiment 1
[0029] An anti-swelling agent is a 10% solution of ethylenediamine diacetate.
[0030] The preparation process is as follows: add water to the reaction kettle, add glacial acetic acid, stir evenly, start circulating water, add ethylenediamine dropwise according to the ratio of glacial acetic acid and ethylenediamine 1:1.6, and control the reaction temperature at 50℃± 2 ℃, about 45min to complete the dropwise addition, let stand for 0.5h, and stir.
Embodiment 2
[0032] An anti-expansion agent is a 30% ethylenediamine diacetate solution.
[0033] Its preparation process is with embodiment 1.
Embodiment 3
[0035] An anti-expansion agent is a 50% ethylenediamine diacetate solution.
[0036] Its preparation process is with embodiment 1.
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The invention discloses an anti-swelling shrinking agent which is an ethylene diamine diacetate solution. This solution avoids the adverse factor that traditionally bridge blinding occurs in capturing of large cations, also overcomes the adverse factor that small cations are low in charge density and short in effective life, has a good clay stabilizing function and is also well capable of shrinking swelled clay. The anti-swelling shrinking agent composited by adding magnesium chloride and / or amino trimethylene phosphonic acid has better anti-swelling and shrinking effects. A liquid of the anti-swelling shrinking agent is clear and crystal, has anti-swelling agent higher than 95% and shrinking rate higher than 35%, and is applicable to preventing and solving the clay swelling problem caused in oilfield development.
Description
technical field [0001] The invention belongs to the technical field of clay anti-expansion, and in particular relates to an anti-expansion and contraction agent, which is used to solve the problem of clay expansion caused by oilfield development. Background technique [0002] In oilfield development, drilling, cementing, perforating, fracturing, acidizing, and water injection operations all have foreign fluids entering the oil layer. Due to the inconsistency between the foreign fluid and formation water, the original balance in the formation is destroyed. Clay minerals Water absorption swelling, dispersion, migration occurs, the effective pores of the formation become smaller, and even the throats are blocked, resulting in a decrease in the permeability of the oil layer, which seriously affects the oil production of oil production wells and water injection of water injection wells. [0003] The research on domestic clay anti-swelling agent can be divided into three stages. F...
Claims
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Patent Timeline
Login to View More IPC IPC(8): C09K8/035C09K8/42C09K8/62C09K8/74
CPCC09K8/035C09K8/42C09K8/62C09K8/74C09K2208/12
Inventor 张卫东张瀚澜
Owner XIAN AODE PETROCHEM ENG TECH CO LTD

