A kind of water-based anticorrosion coating and preparation method thereof
A water-based technology for anti-corrosion coatings, applied in anti-corrosion coatings, polyurea/polyurethane coatings, coatings, etc., can solve the problems of toughness, low adhesion of zinc-rich coatings, and utilization efficiency of shielding materials for polluted environments, and achieve convenient operation and high technology easy effect
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[0076] The embodiments of the present invention provide a water-based anti-corrosion coating and a preparation method thereof. The conductive polymer / fullerene composite modified water-based anti-corrosion coating is prepared by stirring and mixing components A and B uniformly; the component A Including the following components: water-based isocyanate curing agent, zinc powder, defoamer, wetting and dispersing agent, anti-sedimentation thixotropic agent, conductive polymer / fullerene composite material, anti-flash rust agent, leveling agent, adhesion promotion agent, anti-rust pigment.
[0077] Preferably, the curing agent is at least one of water-based isocyanate curing agents BA305, XP2451, and XP 2487. BA305 is a crosslinking agent for water-based coatings. Even under pre-diluted conditions, the coating film is still transparent and bright; XP 2451 and XP 2487 is used as a curing agent component of water-based two-component coatings and sealers, and also as an additive to en...
Embodiment 1
[0090] In terms of parts by mass, the raw material formula of component A consists of: 15 parts of BA305, 55 parts of 400 mesh zinc powder, 5 parts of EL-2607, 5 parts of SN-5040, 2 parts of organic bentonite, 2 parts of conductive polymer / fullerene parts, ZT-709 0.5 parts, SN-612 0.5 parts, kh560 3 parts, zinc phosphate 10 parts. The raw material formula of component B is composed of: 6 parts of methyl methacrylate, 20 parts of butyl acrylate, 16 parts of styrene, 15 parts of epoxy resin, 1 part of methacrylic acid, 1 part of acrylamide, and 1.5 parts of hydroxyethyl acrylate , 1.5 parts of emulsifier, 4 parts of initiator, 120 parts of deionized water, 0.4 part of ammonia water.
[0091] Follow the steps below to prepare water-based anti-corrosion coatings
[0092] Step 1. Add fullerene to hydrochloric acid solution and ultrasonically disperse for 1 hour. After the dispersion is uniform, add polyaniline, polythiophene, polypyrrole and its derivative monomers. Stir and mix e...
Embodiment 2
[0101] In terms of parts by mass, the raw material formula of component A consists of: 20 parts of XP2451, 15 parts of 600-mesh zinc powder, 1 part of DF-103, 1 part of SN-5040, 1 part of organic bentonite, 0.5 parts of fumed silica, conductive 2.5 parts of polymer / fullerene composite material, 0.7 parts of ZT-709, 0.8 parts of SN-612, 3.5 parts of kh550, 10 parts of zinc phosphate, 5 parts of iron and titanium powder; component B is made of the following parts by mass: methyl 13 parts of methyl acrylate, 25 parts of butyl acrylate, 12 parts of styrene, 30 parts of epoxy resin, 6 parts of methacrylic acid, 5 parts of acrylamide, 2 parts of hydroxyethyl acrylate, 4 parts of emulsifier, 5 parts of initiator , 130 parts of deionized water, 0.4 part of ammonia water.
[0102] Follow the steps below to prepare water-based anti-corrosion coatings
[0103] Step 1. Add fullerene to hydrochloric acid solution, and carry out ultrasonic dispersion for 30 minutes. After the dispersion is...
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