Graphene microchip-nano silver cable material and preparation method and application thereof

A technology of graphene microflakes and nano-silver wires, which is applied in the field of cable materials, can solve the problems of easy agglomeration of filling additives, large filling volume of additives, cumbersome processing technology, etc., and achieve low cost, guaranteed quality, and easy raw material components. The effect

Pending Publication Date: 2019-08-09
JIANGSU SHANGSHANG CABLE GRP NEW MATERIAL CO LTD
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, in the prior art, there are problems such as large amount of additive filling, easy

Method used

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  • Graphene microchip-nano silver cable material and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 2

[0028] S1. Prepare silver nanowires with reference to Example 2 in the invention application whose application number is 2019100416626 (publication number 109676150A, publication date 2019-04-26);

[0029] S2. prepare graphene microchip ethylene glycol solution: the mixture of graphene microchip and ethylene glycol is stirred and dispersed, and when the graphene microchip is all immersed in ethylene glycol solution, the suspension of gained is ultrasonically dispersed to obtain Graphene microsheet ethylene glycol solution with a mass concentration of 5%, the mixing and dispersing temperature is controlled at 165-170°C, the ultrasonic dispersion time is 10 minutes, and the frequency is 20000Hz;

[0030] S3. Add nano-silver wires to the graphene microchip ethylene glycol solution in an ultrasonically dispersed environment. After the dispersion is uniform, place it in a microwave reaction device for microwave treatment. The microwave treatment power is 400W and the time is 6min. P...

Embodiment 1

[0032] Weigh the following raw materials: Sinopec LLDPE 7042 resin 70kg, Yangba (Yangzi BASF) 6110MCEVA resin 25kg, antioxidant (a mixture of antioxidant 1010 and antioxidant 168 with a weight ratio of 1:1) 0.6kg, polyethylene Wax (RLC657, industrial grade) 2kg, zinc stearate 0.3kg, fluoride external lubricant (ZB-74) 0.8kg, graphene microsheet-nano silver composite material 4kg.

[0033] Utilize above-mentioned raw material to prepare graphene microchip-nanometer silver wire cable material, specifically comprise the following steps:

[0034] (1) EVA resin, antioxidant and graphene microchip-nano-silver composite material in the above-mentioned raw materials are added in the banbury mixer, and at banbury temperature is 90 ℃, banbury 8min;

[0035] (2) After step (1) is finished, add LLDPE resin, polyethylene wax, zinc stearate and fluoride external lubricant into the internal mixer of step (1), and process at 140°C for 12 minutes;

[0036] (3) extruding and granulating the pr...

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Abstract

The invention discloses a graphene microchip-nano silver cable material and a preparation method and application thereof. The graphene microchip-nano silver cable material is prepared from, by mass, 65-80 parts of LLDPE resin, 15-30 parts of EVA resin, 0.5-1 part of an antioxidant, 1-4 parts of polyethylene wax, 0.2-0.5 part of zinc stearate, 0.5-1 part of an external fluoride lubricant and 3-6 parts of a graphene microchip-nano silver composite material. The graphene microchip-nano silver cable material has high thermal conductivity and an excellent antistatic effect and can be applied to cable sheaths with antistatic performance and high thermal conductivity, the use effect is better, the quality of cable products is guaranteed, and raw material components are simple, easy to obtain andlow in cost. The preparation method has the advantages that the procedures are simple, the operation is easy, and the controllability is high.

Description

technical field [0001] The invention relates to a graphene microchip-nanometer silver wire cable material, a preparation method and application thereof, belonging to the field of cable materials. Background technique [0002] The wire and cable industry has always been the second largest production industry after the automobile industry in China. With the development of the wire and cable industry, the expansion of polyethylene wire and cable applications is gradually expanding. Therefore, for antistatic, high Thermal cable materials are also gradually increasing. However, in the prior art, there are problems such as large filling amount of additives, easy agglomeration of filling additives, uneven dispersion, cumbersome processing technology and the like. Contents of the invention [0003] The invention provides a graphene microchip-nanometer silver wire cable material, its preparation method and application thereof. The graphene microchip-nano silver wire cable material...

Claims

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Application Information

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IPC IPC(8): C08L23/08C08K3/04C08K7/06C08K5/098
CPCC08K2201/011C08L23/0815C08L2201/04C08L2203/202C08L23/0853C08K3/042C08K7/06C08K5/098
Inventor 陶圣熹刘雄军狄洪杰
Owner JIANGSU SHANGSHANG CABLE GRP NEW MATERIAL CO LTD
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