Liquid crystal display device
By controlling the polarization of light by utilizing the thickness direction phase difference of the substrate and the characteristics of the optical compensation layer in the liquid crystal display device, the problem of insufficient black brightness in the oblique direction in the liquid crystal display device is solved, and sufficient black display when viewed from the oblique direction is achieved.
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[0094] Hereinafter, although an Example demonstrates this invention concretely, this invention is not limited to these Examples. The evaluation items in the examples are as follows.
[0095] (1) Product A×E
[0096] Calculated using optical simulation. In the optical simulation, the LCD Master Simulator "LCD MASTER Ver.3.1.3" manufactured by Shintech Co., Ltd. was used to calculate the wavelength 450nm to 650nm in the direction of the azimuth angle of 45° and the polar angle of 60° using the extended function of LCD Master The azimuth angle of the outgoing polarized light of the light, the difference between its maximum value and minimum value is set as A. In addition, the ellipticity of outgoing polarized light of light with a wavelength of 450 nm to 650 nm in directions of an azimuth angle of 45° and a polar angle of 60° is calculated, and the difference between the maximum value and the minimum value thereof is defined as E.
[0097] (2) Maximum black brightness
[0098...
manufacture example 1
[0099] [Manufacturing example 1: Production of a visual recognition side polarizing plate]
[0100] As the thermoplastic resin substrate, use a long amorphous isophthalic acid-copolyethylene terephthalate film (thickness: 100 μm) with a Tg of about 75°C, and apply it to one side of the resin substrate. Corona treatment.
[0101] 100 wt. 13 parts by weight of potassium iodide was dissolved in water to prepare an aqueous PVA solution (coating solution).
[0102] The above-mentioned PVA aqueous solution was applied on the corona-treated surface of the resin substrate and dried at 60° C. to form a PVA-based resin layer with a thickness of 13 μm to produce a laminate.
[0103] The obtained laminate was uniaxially stretched to 2.4 times in the longitudinal direction (length direction) in an oven at 130° C. (in-air auxiliary stretching treatment).
[0104] Next, the laminated body was immersed for 30 seconds in an insolubilization bath (an aqueous boric acid solution obtained by m...
manufacture example 2
[0112] [Manufacturing example 2: Fabrication of rear-side polarizing plate]
[0113] It carried out similarly to manufacture example 1, and obtained the laminated body which has the structure of a resin base material / 2nd polarizer. A TAC film (thickness: 20 μm) was bonded to the polarizer surface (the surface opposite to the resin substrate) of the obtained laminate as an inner protective layer. Next, the resin substrate was peeled off, and a reflective polarizer (26 μm in thickness) was bonded to the peeled surface through an adhesive layer (12 μm in thickness) to obtain a configuration having a reflective polarizer / second polarizer / inner protective layer The back side polarizer.
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