Single branch heparin-binding growth factor analogs
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example 1
[0190]A compound of the present invention was synthesized by solid phase peptide chemistry with the general structure of formula I wherein X is a BMP-2 receptor binding amino acid sequence having the sequence AISMLYLDEKVVL(SEQ ID NO:105) wherein the sequence was grown in parallel from the R1 trifunctional amino acid of formula I when R2 is 0 atoms and R1 is lysine. The resulting synthetic growth modulator analog is of the following specific structure:
and is sometimes called B2A2-K-NS. In the foregoing structure, “Ahx” is 6-amino hexanoic acid, sometimes also called “6-Ahx” or “Hex”. The single letters are standard amino acid single letter abbreviations for the naturally coded amino acids.
example 2
[0191]A compound of the present invention was synthesized by solid phase peptide chemistry with the general structure of formula I wherein X is a BMP receptor binding amino acid sequence having the sequence LYFDESSNVILKK(SEQ ID NO:106) which was grown in parallel from the R1 trifunctional amino acid of formula I when R2 is 0 atoms and R1 is a lysine. The resulting synthetic growth modulator analog is of the following specific structure:
and is sometimes called B7A1-K-NS. In the foregoing structure, “Ahx” is 6-amino hexanoic acid, sometimes also called “6-Ahx” or “Hex”. The single letters are standard amino acid single letter abbreviations for the naturally coded amino acids.
example 3
[0192]A compound of the present invention is synthesized by solid phase peptide chemistry with the general structure of formula I wherein X is a BMP-2 receptor binding amino acid sequence having the sequence ISMLYLDENEKVVLKNY(SEQ ID NO:30) grown in parallel from an R1 trifunctional amino acid of formula I and wherein R1 is lysine. The resulting synthetic growth modulator analog is of the following specific structure:
[0193]In the foregoing structure, “Ahx” is 6-amino hexanoic acid, sometimes also called “6-Ahx” or “Hex”. The single letters are standard amino acid single letter abbreviations for the naturally coded amino acids.
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