Simplified control of color shifting properties of a chiral liquid crystal polymer

a liquid crystal polymer and color shifting technology, applied in the direction of boron compounds, rubidium/caesium/francium compounds, lithium compounds, etc., can solve the problems of mislead consumers and retailers, become even more serious, and difficult to obtain a specific and controlled color shift to a predetermined wavelength

Active Publication Date: 2012-06-07
SICPA HLDG SA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0015]It has surprisingly been found that the incorporation of a relatively inexpensive class of substances into a chiral liquid crystal polymer precursor composition influences the color-shifting properties of the composition in an efficient and predictable manner and thereby eliminate

Problems solved by technology

Counterfeit is no longer a national or a regional problem but a worldwide problem which has an impact not only on manufacturers but also on the consumer.
Counterfeiting is a significant problem with goods like clothes and watches but becomes even more serious when it affects medicines and drugs.
Counterfeiting has also an impact on government revenues in that it affects the collection of taxes for, e.g., cigarettes and alcohol because of the existence of a black market where it is impossible to track and trace counterfeit (smuggled, diverted, etc.) products with no valid tax stamps.
Like for many other security features which are used in the market, there is always the temptation for counterfeiters to reproduce these security features and therefore misleads consumers and retailers.
It is difficult to obtain a specific and controlled color shift to a predetermined wavelength, as a number of parameters (temperature, nature of substrate, e

Method used

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  • Simplified control of color shifting properties of a chiral liquid crystal polymer
  • Simplified control of color shifting properties of a chiral liquid crystal polymer
  • Simplified control of color shifting properties of a chiral liquid crystal polymer

Examples

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examples

Preparation of a Chiral Liquid Crystal Precursor Composition

[0087]A chiral liquid crystal precursor composition (I) was prepared as follows, the indicated percentages being by weight based on the total weight of the composition:

[0088]A chiral dopant compound B of formula (I) shown above (4.75%), a nematic compound A1 (14%), a nematic compound A2 (14%), and cyclohexanone (66.45%) were placed into a flask which was thereafter heated until a solution was obtained. To the solution were added 2-methyl-1[4-(methylthio)phenyl]-2-morpholinopropan-1-one (Irgacure 907® from Ciba, photoinitiator, 0.6%) and isopropylthioxanthone (photoinitiator, 0.2%). The final mixture was stirred until complete dissolution was achieved to result in the chiral liquid crystal precursor composition (I).

Preparation of a Layer of a Cured Chiral Liquid Crystal Precursor Composition

[0089]The above composition (I) was coated on a substrate (transparent PET film, thickness 125 μm) and the resultant layer was heated to...

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Abstract

A chiral liquid crystal precursor composition which comprises at least one salt that changes a position of the selective reflection band exhibited by the composition in a cured state compared to the position of a selective reflection band exhibited by a composition in the cured state that does not contain the at least one salt. This abstract is neither intended to define the invention disclosed in this specification nor intended to limit the scope of the invention in any way.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]The present application claims the benefit under 35 U.S.C. §119(e) of U.S. Provisional Application No. 61 / 420,582, filed Dec. 7, 2010 and claims priority under 35 U.S.C. §119 of International Patent Application No. PCT / EP2010 / 069051, filed Dec. 7, 2010. The entire disclosures of these applications are expressly incorporated by reference herein.BACKGROUND OF THE INVENTION[0002]1. Field of the Invention[0003]The present invention relates to a simplified process for controlling the color-shifting properties of chiral nematic (also called cholesteric) liquid crystal polymers. In particular, the invention relates to controlling the color-shifting properties of a chiral liquid crystal polymer by incorporating therein one or more salts which are capable of changing the position of the selective reflection band (color) of the polymer. Correspondingly modified chiral liquid crystal polymers are useful, for example, for marking purposes.[0004]2. Di...

Claims

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Application Information

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IPC IPC(8): B32B3/10C01B11/18C01D15/10C01B35/06C01D15/04B05D5/00C01D3/04C01D9/00C07C211/63C07F5/02B05D3/02B05D3/06C09K19/52C01D7/00
CPCC09K19/54Y10T428/24802C09K2019/0448C09K19/588C09K19/58
Inventor CALLEGARI, ANDREAJAUZEIN, TRISTAN
Owner SICPA HLDG SA
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