Crosslinked products prepared by ionically crosslinking a solid grade oligomer and a polymer using an ionic crosslinking agent and methods of making the same
a technology of ionic crosslinking agent and solid grade oligomer, which is applied in the field of compositions, can solve the problems of less effective sulfur-based crosslinking agent in certain lower temperature applications
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[0074]A copolymer derived from 50 parts by weight styrene, 50 parts by weight butadiene, and 20 parts by solid grade oligomer (SGO B-98) was produced. A styrene feed, a butadiene feed, an initiator feed comprising an aqueous solution of sodium persulfate initiator (0.6 parts by weight of the total monomers), were added over 6 hours to a pre-heated reactor (70° C.) containing water, the solid grade oligomer, sodium hydroxide (0.14 parts by weight of the total monomers), a polystyrene seed latex (1.66 parts by weight of the total monomers), and TRILON BX (0.03 parts by weight of the total monomers), an ethylenediaminetetraacetic acid commercially available from BASF Corporation (Florham Park, N.J.). The stabilization of the latex partides during polymerization was accomplished by feeding an aqueous solution of potassium oleate surfactant (3.6 parts by weight of the total monomers) over the course of the polymerization. The temperature was maintained at 70° C. throughout the polymeriza...
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