Method of manufacturing a mould part
a manufacturing method and mould technology, applied in the direction of coatings, electrolytic processes, chemical instruments and processes, etc., can solve the problems of mould parts with a surface that is not a perfect reverse image, alloying elements form oxides which are not easily removed, and the pure aluminium is not suitable for chip-producing processing, etc., to achieve smoothening properties and better surface treatment. , the effect of improving the surface treatmen
Inactive Publication Date: 2010-08-03
DANMARKS TEKNISKE UNIV
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Benefits of technology
[0006]The object of the invention is to provide an improved method of making a mould part, in which the surface of the mould part is a perfect reverse image of the article to be manufactured by the mould part, and which method provides environmental advantages compared to known methods.
[0013]Depositing a copper layer on top of the master prior to the nickel plating, all oxides and other chemical combinations formed by the alloying elements of the aluminium alloy or the zinc alloy are left on the surface of the copper deposition and is removed with the copper in the alkaline etchant. As the alkaline etchant does not dissolve nickel, a perfectly shaped and clean surface for moulding articles is obtained. This perfectly shaped surface is a great advantage, when the mould part is used for forming high precision parts. No dangerous chemicals, such as cyanide based alkaline solutions are needed. Use of solutions based on peroxide, such as mixtures of sulphuric acid or ammonia with peroxide, which are unstable and difficult to use, are avoided.
[0018]According to a further embodiment the oxygen is supplied to the etchant by pumping pure oxygen, atmospheric air or a mixture hereof through the solution. This is a very simple way of providing an oxidizer to the etchant.
[0019]According to a preferred embodiment the master is made of an aluminium alloy, and the master surface is zincated prior to the copper deposition process. Zincating is a process of depositing a thin zinc layer on the aluminium surface. The zinc layer does not form a protective oxide layer as rapidly as aluminium and is therefore a better basis for further surface treatments.
[0020]The copper deposition process is preferably electroplating from an alkaline copper bath, especially a copper pyrophosphate bath. A copper pyrophosphate bath is an environment-friendly bath and is very suitable for plating on zinc, as the zinc layer can survive in the mildly alkaline bath until it is completely covered with copper. A copper layer deposited from the copper pyrophosphate bath also has the advantage that small scratches and other defects in the aluminium surface are smoothened prior to plating the mould layer. However, other copper baths have smoothening properties and are capable of replacing the copper pyrophosphate bath.
Problems solved by technology
Furthermore, it is known to remove the aluminium master by dissolving the aluminium in an alkaline solution.
Pure aluminium is not suitable for chip-producing processing as long chips are produced.
However, several of these alloying elements form oxides which are not easily removed by the alkaline solution.
In most cases, these aggressive solutions will etch or dissolve some of the nickel or cobalt resulting in a mould part with a surface which is not a perfect reverse image of the master.
Method used
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Embodiment Construction
[0006]The object of the invention is to provide an improved method of making a mould part, in which the surface of the mould part is a perfect reverse image of the article to be manufactured by the mould part, and which method provides environmental advantages compared to known methods.
[0007]According to the invention a method of making a mould part for forming an article is provided, said method comprising:[0008]providing a master of an aluminium alloy or a zinc alloy with a surface corresponding to the surface of the article to be formed by the mould part,[0009]depositing a copper layer on top of the master surface,[0010]plating a mould part layer of nickel, a nickel alloy, cobalt or a cobalt alloy on top of the copper layer,[0011]dissolving the master in a solution,[0012]selective etching the copper layer from the mould part layer in an alkaline etchant comprising free Cu(II) ions, a first complexing agent forming strong complexes with Cu(I) ions but not Ni ions or Co ions, a sec...
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Abstract
A method of manufacturing a mould part (8) for forming an article. The method comprises: providing a master (1) of an aluminium alloy or a zinc alloy with a surface (7) corresponding to the surface of the article to be formed by the mould part. A copper layer (3) is deposited on top of the master surface (7). Then a mould part layer (4) of nickel, a nickel alloy, cobalt or a cobalt alloy is plated on top of the copper layer. The master (1) is dissolved in a solution. The copper layer (3) is selectively etched from the mould part layer (4) in an alkaline etchant comprising free Cu(II) ions, a first complexing agent forming strong complexes with Cu(I) ions but not Ni ions or Co ions, a second complexing agent forming strong complexes with Cu(II) ions but not Ni ions or Co ions. Oxygen is supplied to the etchant for oxidizing Cu(I) ions to Cu (II) ions.
Description
TECHNICAL FIELD[0001]The invention relates to a method of manufacturing a mould part for forming an article.BACKGROUND ART[0002]Mould parts, inserts or dies for forming articles are used in many different processes, such as injection moulding, blow moulding, hot pressing, stamping, thermoforming, embossing, coining or printing, etc. The mould part can be manufactured in many different ways. It can be milled from a solid member of metal or other material. Another method is to manufacture the mould by electroforming. A master with the shape of the article to be manufactured by the mould is provided. The master can be of an electrically conductive material or be provided with a surface of an electrically conductive material. A relatively thick “mould layer” of metal is electroplated on the surface of the master. The master is then removed, e.g. by dissolving, and the electrodeposited metal layer can be used as a mould part for forming articles with the same shape as the master. The met...
Claims
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IPC IPC(8): B44C1/22
CPCC25D1/00C25D1/10
InventorTANG, PETER TORBEN
OwnerDANMARKS TEKNISKE UNIV