A kind of high flame retardant and low smoke toxicity sheet molding compound and its preparation method

A sheet molding compound and high flame retardant technology, applied in the field of high flame retardant and low smoke toxicity sheet molding compound and its preparation, can solve the problem of surface quality and mechanical properties decline, decoration or facilities being easily damaged, loss of light weight , high strength and other issues, to achieve the effect of improving flame retardant and smoking properties, reducing heat release rate and improving surface quality

Inactive Publication Date: 2011-12-14
BEIJING ZHONGTIE LONGDRAGON ADVANCED COMPOSITE MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the following methods are generally used for flame retardant treatment of materials: one is to use halogen-containing or phosphorus-containing flame retardants. And produce a large amount of poisonous gas and smog, which will cause great damage to human life safety; the second is to add a large amount of aluminum hydroxide filler. The advantage of this method is that it can simultaneously improve the fire resistance of the material and control the smoke toxicity, but its disadvantages are: The addition of a large amount of ordinary aluminum hydroxide fillers will greatly reduce the surface quality and mechanical properties of the product, and lose its light weight and high strength characteristics, thus making the decoration or installation easily damaged

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Weigh the substance (kg) according to the following mass:

[0024] Unsaturated polyester resin 80kg, low shrinkage additive 20kg, initiator 1.5kg, polymerization inhibitor 0.02kg, wetting and dispersing agent 4kg, internal release agent 4kg, thickener 1kg, viscosity reducing filler 20kg, flame retardant A180kg, Flame retardant B60kg, reinforcing material 92kg.

[0025] Preparation:

[0026] Add 20kg of low-shrinkage additive, 1.5kg of initiator, 0.02kg of polymerization inhibitor, 6kg of wetting and dispersing agent, 4kg of internal release agent, and 1kg of thickening agent into a stirring tank with 80kg of unsaturated polyester resin, and stir until the dispersion is uniform Add 20kg of viscosity-reducing filler, 180kg of flame retardant A, and vigorously stir; turn on the ultrasonic powerful emulsifier, add 60kg of flame retardant B, and vigorously stir to obtain a uniformly dispersed unsaturated polyester paste. Use polyethylene film as a diaphragm, impregnate 25...

Embodiment 2

[0031] Weigh the substance (kg) according to the following mass:

[0032] Unsaturated polyester resin 75kg, low shrinkage additive 30kg, initiator 1.5kg, polymerization inhibitor 0.04kg, wetting and dispersing agent 3.5kg, internal release agent 6kg, thickener 2kg, viscosity reducing filler 40kg, flame retardant A150kg , flame retardant B50kg, reinforcing material 143kg.

[0033] The preparation method is as in Example 1;

[0034] In the foregoing examples, the unsaturated polyester resin is P17-902 (produced by Jinling DSM Resin Co., Ltd.), the low-shrinkage additive is polystyrene H814-901 (produced by Jinling DSM Resin Co., Ltd.), and the initiator is tertiary Butyl peroxide-2-ethylhexanoate, benzoquinone as polymerization inhibitor, BYK-W990 as wetting and dispersing agent, calcium stearate as internal mold release agent, organic bentonite as filler for viscosity reduction, flame retardant A It is aluminum hydroxide ON-906 (produced by Yabao Chemical Co., Ltd., USA), fla...

Embodiment 3

[0038] Weigh the substance (kg) according to the following mass:

[0039] 75kg of unsaturated polyester resin, 20kg of low-shrinkage additive, 1kg of initiator, 0.01kg of polymerization inhibitor, 5kg of wetting and dispersing agent, 5kg of internal release agent, 1kg of thickener, 30kg of viscosity-reducing filler, 180kg of flame retardant A, Fuel B100kg, reinforcing material 83kg.

[0040] The preparation method is as in Example 1;

[0041] In the foregoing examples, the unsaturated polyester resin is P17-901 (produced by Jinling DSM Resin Co., Ltd.), the low-shrinkage additive is thermoplastic resin H870-902, and the initiator is tert-butylperoxy-2-ethylhexanoic acid ester, polymerization inhibitor is benzoquinone, wetting and dispersing agent is BYK-W990, internal release agent is calcium stearate, viscosity reducing filler is 10g WE polyethylene wax, fumed silica 20g, flame retardant A is hydrogen Alumina ON-904 (produced by Yabao Chemical Co., Ltd., USA), flame retarda...

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Abstract

The invention relates to a high-flame-retardance and low-smoke toxicity sheet molding compound and a preparation method thereof. The formula of the plastic contains the following substances in parts by mass: 50-80 parts of unsaturated polyester resin, 15-60 parts of low-shrinkage additive, 1-3 parts of initiator, 0.01-0.05 parts of polymerization inhibitor, 0.7-7 parts of wetting and dispersing agent, 3-8 parts of internal release agent, 1-2 parts of thickener, 20-50 parts of viscosity-reducing filler, 100-200 parts of flame retardant A, 50-100 parts of flame retardant B, 50-250 parts of reinforcing material; the flame retardant A is micron aluminum hydroxide with a particle size of 0.4-3.5 microns, and the flame retardant B It is nano-level aluminum hydroxide with a particle size of 30-80 nanometers. The plastic of the invention has high flame retardancy, low smoke toxicity, and simultaneously has good mechanical properties and surface decoration effects.

Description

technical field [0001] The invention relates to the field of chemical raw materials, in particular to a sheet molding compound with high flame retardancy and low smoke toxicity and a preparation method thereof. Background technique [0002] Decorative materials for vehicles and large public places, especially for large-scale rail transit, not only require high strength, light weight, comfort, and good decorative effects, but also emphasize the safety of decorative and facility materials. As the market continues to develop on a large scale, sheet molding compound molded products have been widely used. This interior material particularly emphasizes its safety, especially the flame retardancy of the material. Therefore, sheet molding compound molded products are used in the production process The raw materials are flame retardant treated. At present, the following methods are generally used for flame retardant treatment of materials: one is to use halogen-containing or phospho...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/06C08K13/02C08K3/22C08K3/36C08K3/34
Inventor 陈跃王大勇李春彦鹿子娟
Owner BEIJING ZHONGTIE LONGDRAGON ADVANCED COMPOSITE MATERIAL
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