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87results about How to "Reduce smoke production" patented technology

Graphene grafted nitrogen, phosphorus and silicon synergistic halogen-free flame retardant and preparation method thereof

ActiveCN109180952AAchieve halogen-free synthesisGive full play to the multiple synergistic flame retardant effectIn situ polymerizationNitrogen
The invention belongs to the technical field of fire retardants and mainly relates to a graphene grafted nitrogen, phosphorus and silicon synergistic halogen-free flame retardant and a preparation method thereof. The preparation method comprises the following steps: compounding 3-aminopropyl-triethoxysilane into octa-aminopropyl caged silsesquioxane through a hydrolytic condensation polymerizationprocess; preparing graphene oxide after chemically oxidizing and peeling graphene through an improved hummers process; compounding 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and graphene oxide into a grafted product 1 with an reactivity functional group through an in situ polymerization process; grafting the octa-aminopropyl caged silsesquioxane and the grafted product 1 into the graphenegrafted nitrogen, phosphorus and silicon synergistic halogen-free flame retardant through the in situ polymerization process. The preparation method for the graphene grafted nitrogen, phosphorus andsilicon synergistic halogen-free flame retardant provided by the invention has the advantages of simple preparation process, safety, environmental friendliness, and the like; the graphene grafted nitrogen, phosphorus and silicon synergistic halogen-free flame retardant can be widely used for inflaming retarding in the fields of electronics, automobiles, cables, packaging, aviation, and the like; the graphene grafted nitrogen, phosphorus and silicon synergistic halogen-free flame retardant has a bright application prospect.
Owner:SICHUAN UNIV

Modified expandable graphite, flame retardant as well as preparation method and application thereof in polyurethane foam

The invention relates to the technical field of flame retardants, and specifically relates to modified expandable graphite, a flame retardant, a preparation method and application thereof in polyurethane foam, and the modified expandable graphite is characterized in that one or more layer of polymer surface modifying agents with special functional groups is /are adsorbed on the surface of expandable graphite, the preparation method of the modified expandable graphite comprises: carrying out surface modification on the expandable graphite by using an organic modifier containing hydroxyl and a polar six-membered ring structure, adding a dispersing agent, uniformly mixing, and crushing and sieving to obtain the modified graphite; after adding of the modified graphite into polyurethane composite polyether according to a certain ratio and uniform mixing, the modified graphite can be uniformly dispersed and suspended in the polyether; the flame retardancy of the obtained polyurethane thermalinsulation material is greatly improved, the other performances of the polyurethane rigid foam are not influenced, the flame retardancy is good, the flame retardant effect is durable, the oxygen index is greatly improved, and the heat release rate peak value is greatly reduced.
Owner:WEIHAI YUNSHAN TECH

Nitrogen-phosphorus-silicon modified graphene halogen-free flame retardant polymer composite material and preparation method thereof

The invention belongs to the technical field of macromolecular materials, and relates to a nitrogen-phosphorus-silicon modified graphene halogen-free flame retardant polymer composite material and a preparation method thereof, wherein the composite material is prepared from the following substances in parts by weight: 60-90 parts of a polymer, and 10-40 parts of a nitrogen-phosphorus-silicon modified graphene flame retardant. All the components are weighed according to the weight percentage and are mixed uniformly, and then the mixture is added into a twin-screw extruder, melted and mixed andthen subjected to injection molding into corresponding sample strips by an injection moulding machine, or the mixture is melted and blended by an internal mixer and is subjected to compression moulding forming by a mould with a certain size on a plate vulcanizing machine, or a method of solidifying moulding by a curing agent is adopted. The nitrogen-phosphorus-silicon modified graphene halogen-free flame retardant polymer composite material provided by the invention has the advantages of high charring property, and excellent flame retardancy and thermal stability, and can be applied to flame retardancy of materials such as electric cables, automobiles and packages.
Owner:SICHUAN UNIV

Polyimide foam composite material, and preparation method and application thereof

The invention provides a polyimide foam composite material, and a preparation method and application thereof. The preparation method comprises the following steps: adding aromatic dianhydride into a tetrahydrofuran/methanol mixed solvent, carrying out heating to dissolve the aromatic dianhydride and carry out an esterification reaction, adding aromatic diamine and a foam stabilizer after the solution is transparent, and uniformly carrying out mixing to obtain a foam precursor solution; drying the foam precursor solution, then crushing the dried solid product to obtain polyester ammonium salt powder, and carrying out foaming and a preliminary imidization reaction to prepare partially imidized polyimide foam; and cutting the partially imidized polyimide foam, then carrying out thermal compounding on the cut product and a reinforcing material, and then carrying out a complete imidization reaction on the product obtained after the thermal compounding to obtain the polyimide foam compositematerial. The polyimide foam composite material provided by the invention has good flame retardancy, heat insulation performance, scratch resistance, and tear and tensile properties, and is low in smoke production amount during high-temperature baking and decomposition;
Owner:BEIJING RADIATION APPL RES CENT

Composite halogen-free flame-retardant smoke suppression agent of PVC wood-plastic composite material and preparation method and application of agent

InactiveCN105566811AAdvantages of flame retardant and smoke suppression effectAdd lessPentaerythritolCombustion
The invention relates to a composite halogen-free flame-retardant smoke suppression agent of a PVC wood-plastic composite material and a preparation method and application of the agent, which relate to the composite halogen-free flame-retardant smoke suppression agent and the preparation method and application of the agent, and aim at solving the problems that the PVC wood-plastic composite material is combustible, a great amount of smoke is produced when the composite material is combusted, the addition amount of the existing PVC wood-plastic composite material flame-retardant smoke suppression agent is large, the flame-retardant effect and the smoke suppression effect are poor, and the existing PVC wood-plastic composite material flame-retardant smoke suppression agent is harmful to the health of people. The composite halogen-free flame-retardant smoke suppression agent consists of ammonium polyphosphate, melamine, pentaerythritol and copper oxide. The preparation method comprises the following steps: I, preparing an expansion-type flame-retardant agent; II, preparing the composite halogen-free flame-retardant smoke suppression agent. The application method comprises the following steps: I, weighing raw materials; II, preparing high-temperature materials; III, preparing a premix; IV, extruding and forming. The flame-retardant smoke suppression agent solves the problems that the wood-plastic composite material is combustible, a great amount of smoke is produced when the composite material is combusted, the addition amount of the existing flame-retardant smoke suppression agent is large, the effect is poor, and the existing flame-retardant smoke suppression agent is harmful to the health of people. The composite halogen-free flame-retardant smoke suppression agent is used for resisting the combustion and suppressing the smoke of the PVC wood-plastic composite material.
Owner:白晓艳

Flame-retardant type polyurethane rigid foam and preparation method thereof

The invention discloses a flame-retardant type polyurethane rigid foam and a preparation method thereof, and relates to the technical field of processing of materials. The flame-retardant type polyurethane rigid foam and the preparation method have the advantages that the surface of basalt fiber is modified by phosphoric acid to obtain the phosphoric acid-modified basalt fiber, so that the surfaceactivity of the basalt fiber is improved; the phosphoric acid-modified basalt fiber is mixed with phosphotriester-(2-isopropyl chloride) to form a flame-retardant agent for preparing the flame-retardant type polyurethane rigid foam, so as to solve the problems of poor compatibility and low mechanical property due to direct compounding of the basalt fiber and the polyurethane rigid foam matrix, and reach the technical effects of accelerating the formation of a crosslinking network of a polyurethane foam system and improving the mechanical property of the flame-retardant type polyurethane rigidfoam; the phosphoric acid-modified basalt fiber and the phosphotriester-(2-isopropyl chloride) as the flame-retardant agent can be uniformly dispersed into the flame-retardant type polyurethane rigidfoam matrix, so as to reduce the heat release rate and smoke production amount of the polyurethane foam, and reach better flame-retardant and smoke-inhibiting properties of the polyurethane foam.
Owner:JIAXING UNIV
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