The present application relates to the technical field of
high polymer material
flame-retardant modification, and particularly relates to a COF hierarchical modification APP-based core-shell
flame-retardant
smoke suppressant, a preparation method and application thereof. The
flame-retardant
smoke suppressant takes APP as a flame-retardant core layer; takes PVP as a soft template agent, and assists in situ growth of
melamine-p-phenylenedimethylene
formaldehyde (COF) on the surface of APP to adsorb combustible volatile components in the initial
pyrolysis stage, provide a gas source, and act as a Fe 3+ coordination skeleton; takes
tannic acid as a coordination agent and a
carbon source, and constructs a multi-level core-shell structure with Fe 3+ coordination. The present application realizes integration of flame-retardant and
smoke suppression functions through hierarchical modification. When the flame-retardant agent is applied to
polyurethane, it can significantly reduce the heat release rate, smoke release rate and
toxic gas generation amount, and simultaneously improve the compatibility with the matrix, effectively overcoming the defects of poor compatibility and insufficient flame-retardant and smoke suppression performance of traditional APP flame-retardant agents. The present application has simple preparation process and controllable conditions, and is suitable for industrial production.