The invention relates to technical field of building fire protection, and discloses an energy-saving aluminum alloy fire window. The energy-saving aluminum alloy fire window comprises a window frame,the window frame comprises four frames, a sash is hinged to one of the vertical frames, a plurality of separating plates are fixed in the frames and divide the inner part of the frames into a plurality of cavities, the cavities are provided with fire-fighting assemblies, the fire-fighting assemblies comprise shells fixed to the separating plates, the shells are piled with carbonate powder, liquidbags loaded with concentrated acid solutions are fixed to the top walls of the shells, expansion blocks made from thermal expansion materials are fixed to the inner side walls of the shells, spikes for piercing the liquid bags are fixed to the sides, facing the liquid bags, of the expansion blocks, and air outlet pipes communicating with indoor air further communicate with the tops of the shells.According to the scheme, when the fire window suffers heat, the spikes pierce the liquid bags, concentrated acid in the liquid bags reacts with the carbonate in the shells to generate carbon dioxide,the carbon dioxide enters indoor along the air outlet pipes, thus the oxygen concentration indoor is lowered, and the purposes of fire propagation containment even flame putting out are achieved.