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5-chloronitroaniline-containing dye

A technology of chloronitroaniline and dyes, which is applied in the direction of azo dyes, organic dyes, monoazo dyes, etc. It can solve the problems of difficult dyeing depth and poor washing fastness, and achieve excellent moisture resistance, good temperature dependence, and washing Excellent fastness effect

Active Publication Date: 2012-12-05
连云港澄鑫化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But they have poor washing fastness and are difficult to dye deep, especially in the case of polyester and spandex blends, it is even more difficult to dye deep, and the washing fastness is even worse

Method used

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  • 5-chloronitroaniline-containing dye
  • 5-chloronitroaniline-containing dye
  • 5-chloronitroaniline-containing dye

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Add 21.8 grams of 5-chloro-2,4-dinitroaniline to 50 milliliters of sulfuric acid, add 13 grams of nitrosyl sulfuric acid dropwise at room temperature, and stir for 4 hours. After the diazonium reaction is completed, add the In the mixture of 15 milliliters of sulfuric acid, 500 grams of ice water and 28 grams of compounds shown in formula (II-1),

[0025] Formula (II-1)

[0026] After adding, continue to react for 1 hour, add 500 milliliters of water, slowly rise to 60 ℃ and keep warm for 1 hour, suction filtration, obtain the azo dye containing 5-chloronitroaniline shown in formula (I-1):

[0027] Formula (I-1)

[0028] The polyester fiber is dyed to obtain a blue dyed product with excellent fastness properties.

Embodiment 2

[0030] Add 30 grams of 5-chloro-6-bromo-2,4-dinitroaniline to 50 ml of sulfuric acid, add 13 grams of nitrosyl sulfuric acid dropwise at room temperature, and stir for 4 hours. Add the following to the mixture consisting of 15 milliliters of sulfuric acid, 500 grams of ice water and 28 grams of compounds shown in formula (II-2),

[0031] Formula (II-2)

[0032] After adding, continue to react for 1 hour, add 500 milliliters of water, slowly rise to 60 ℃ and keep warm for 1 hour, suction filtration, obtain the azo dye containing 5-chloronitroaniline shown in formula (I-2):

[0033]

[0034] Formula (I-2)

[0035] The polyester fiber is dyed to obtain a purple dyed product with excellent fastness properties.

Embodiment 3-30

[0037] Adopt the method synthesis of embodiment 1 or 2 to contain 5-chloronitroaniline azo compounds as shown in formula (I-3), wherein various substituting groups are defined in table 1, can be used for polyester fiber dyeing , has good washing fastness.

[0038]

[0039] R 4 : H, -CH 3 、-OC 2 h 5 , -NHCOCH 3

[0040] Formula (I-3)

[0041] Table 1

[0042]

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PUM

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Abstract

The invention discloses a 5-chloronitroaniline-containing azoic compound as well as a preparation method and an application thereof. The 5-chloronitroaniline-containing azoic compound is as shown in a formula (I), wherein each group is defined in the specification. A dye containing the 5-chloronitroaniline-containing azoic compound is used for dyeing polyesters, terylenes, terylene superfine fibers and blended fabrics of the terylene superfine fibers and polyurethanes, and has the advantages of excellent washing resistance, friction resistance, light resistance and sublimation fastness.

Description

A technical field [0001] The invention relates to an azo compound containing 5-chloronitroaniline, a preparation method and an application thereof, and belongs to the technical field of chemical material preparation. Two background technology [0002] 2,4-dinitro-6-bromo (or chloro) aniline is used as a disperse dye of the diazo component of the dye, mostly dark varieties, widely used in polyester, polyester and other fabrics, such as C.I. Disperse Blue 79:1 , Disperse Blue 291, Disperse Violet 93, etc. However, they have poor washing fastness and are difficult to dye deep, especially in the case of polyester and spandex blends, it is even more difficult to dye deep, and the washing fastness is even worse. Therefore, there is a need for an economical new dye with good depth and high wash fastness. Three invention content [0003] The object of the present invention is to provide a kind of azo compound containing 5-chloronitroaniline, which has excellent deep color dyeing...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09B29/01C09B67/38C09B67/22D06P1/18D06P3/54
Inventor 陆建焕谢毅李萍方东
Owner 连云港澄鑫化工有限公司
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