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Composite reinforced PBT material and preparation method thereof

A composite reinforcement and PBT resin technology, applied in the field of composite reinforcement materials, can solve the problems of reducing the physical and mechanical properties of materials and processing fluidity, low notched impact strength, large molding shrinkage, etc., and achieve excellent environmental protection, flame retardancy, and stable dimensions The effect of high resistance and good mechanical properties

Active Publication Date: 2016-01-20
JIANGSU KINGFA SCI & TECH ADVANCED MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Polybutylene terephthalate, referred to as PBT, is polymerized by polycondensation of terephthalic acid and butanediol. Its melting point is 225°C to 235°C. It is milky white translucent to opaque, crystalline thermoplastic Polyester has the advantages of high heat resistance, toughness, fatigue resistance, self-lubrication, low friction coefficient, etc. It is widely used in electronic appliances, coil bobbins, electrical connectors, auto parts and other fields, but it still has low notched impact strength , high molding shrinkage, easy to burn, long molding cycle and other defects limit its application range. For this reason, extensive modification research has been carried out on PBT at home and abroad, mainly toughening, strengthening, flame retardant and blending modification. However, the flame retardants currently used to prepare flame-retardant PBT are mainly phosphorus-based and halogen-based flame retardants. These flame retardants will not only significantly reduce the physical and mechanical properties and processing fluidity of the material, but also have an impact on the environment. Therefore, there is an urgent need for a composite reinforced PBT material that not only has excellent flame retardancy, but also has good environmental protection characteristics, mechanical properties, high dimensional stability, and high gloss.

Method used

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  • Composite reinforced PBT material and preparation method thereof
  • Composite reinforced PBT material and preparation method thereof
  • Composite reinforced PBT material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] 40 parts by weight of PBT resin, 6 parts by weight of composite modifier, 1 part by weight of siloxane flame retardant, 3 parts by weight of sulfonate flame retardant, 45 parts by weight of high aspect ratio inorganic filler, 0.4 part by weight of anti- Oxidant, 0.6 parts by weight of processing aid and 4 parts by weight of coupling agent are added in a high-mixer, and mixed uniformly at room temperature; the twin-screw extruder is used to carry out extrusion granulation, and the process conditions for extrusion granulation are: 1. Zone temperature 220℃~240℃, zone 2 temperature 230℃~245℃, zone 3 temperature 235℃~245℃, zone 4 temperature 235℃~250℃, zone 5 temperature 220℃~240℃, zone 6 temperature 220℃~ 240°C, the temperature in the seventh zone is 210°C-230°C, the temperature in the eighth zone is 200°C-220°C, the temperature in the ninth zone is 200°C-220°C, the temperature in the tenth zone (machine head) is 220°C-240°C, and the screw speed is 200 rpm Between -450 rpm;...

Embodiment 2

[0023] 50 parts by weight of PBT resin, 7 parts by weight of composite modifier, 1 part by weight of siloxane flame retardant, 3 parts by weight of sulfonate flame retardant, 35 parts by weight of high aspect ratio inorganic filler, 1.5 parts by weight of anti- Oxidant, 0.5 parts by weight of processing aid and 2 parts by weight of coupling agent are added in a high-mixer, and mixed uniformly at room temperature; the twin-screw extruder is used for extrusion granulation, and the process conditions for extrusion granulation are: 1. Zone temperature 220℃~240℃, zone 2 temperature 230℃~245℃, zone 3 temperature 235℃~245℃, zone 4 temperature 235℃~250℃, zone 5 temperature 220℃~240℃, zone 6 temperature 220℃~ 240°C, the temperature in the seventh zone is 210°C-230°C, the temperature in the eighth zone is 200°C-220°C, the temperature in the ninth zone is 200°C-220°C, the temperature in the tenth zone (machine head) is 220°C-240°C, and the screw speed is 200 rpm Between -450 rpm; then co...

Embodiment 3

[0025] 55 parts by weight of PBT resin, 8 parts by weight of composite modifier, 2 parts by weight of siloxane flame retardant, 2 parts by weight of sulfonate flame retardant, 30 parts by weight of high aspect ratio inorganic filler, 0.5 parts by weight of anti Oxidant, 0.5 parts by weight of processing aid and 2 parts by weight of coupling agent are added in a high-mixer, and mixed uniformly at room temperature; the twin-screw extruder is used for extrusion granulation, and the process conditions for extrusion granulation are: 1. Zone temperature 220℃~240℃, zone 2 temperature 230℃~245℃, zone 3 temperature 235℃~245℃, zone 4 temperature 235℃~250℃, zone 5 temperature 220℃~240℃, zone 6 temperature 220℃~ 240°C, the temperature in the seventh zone is 210°C-230°C, the temperature in the eighth zone is 200°C-220°C, the temperature in the ninth zone is 200°C-220°C, the temperature in the tenth zone (machine head) is 220°C-240°C, and the screw speed is 200 rpm Between -450 rpm; then co...

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Abstract

The invention discloses a composite and reinforced PBT (polybutylece terephthalate) material and a preparation method thereof. The material comprises the following components in percentage by weight: 40-65 percent of PBT resin, 6-9 percent of compound modifier, 1-3 percent of siloxane flame retardant, 1-3 percent of sulfonates flame retardant, 20-45 percent of inorganic filler with high aspect ratio, 0.4-1.6 percent of antioxidant, 0.4-0.6 processing agent and 1-4 percent of coupling agent. The material provide by the invention has not only excellent flame retardant property, but also the advantages of good environmental protection characteristic, good mechanical property, high dimensional stability, high gloss and the like, and can be widely used in products of electric products, coil frameworks, electrical connectors, automobile parts and the like so as to enable the PBT resin to have broad application prospect.

Description

technical field [0001] The invention relates to a composite reinforced material, in particular to a composite reinforced PBT material and a preparation method thereof, which can be widely used in the fields of electronic appliances, coil frames, electrical connectors, auto parts and the like. Background technique [0002] Polybutylene terephthalate, referred to as PBT, is polymerized by polycondensation of terephthalic acid and butanediol. Its melting point is 225°C to 235°C. It is milky white translucent to opaque, crystalline thermoplastic Polyester has the advantages of high heat resistance, toughness, fatigue resistance, self-lubrication, low friction coefficient, etc. It is widely used in electronic appliances, coil bobbins, electrical connectors, auto parts and other fields, but it still has low notched impact strength , high molding shrinkage, easy to burn, long molding cycle and other defects limit its application range. For this reason, extensive modification resear...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L67/02C08L23/08C08K13/04C08K7/10C08K7/02C08K5/5415C08K5/42B29B9/06B29C47/92B29C48/92
CPCB29C48/40B29C48/625B29C48/875B29C48/92B29C2948/9259B29C2948/92704B29C2948/92885B29C2948/92895
Inventor 钟鲁刘志雄杨碎平
Owner JIANGSU KINGFA SCI & TECH ADVANCED MATERIALS CO LTD