Polyvinyl alcohol anion-exchange membrane and preparation method thereof

An anion exchange membrane, polyvinyl alcohol technology, applied in the field of chemistry, can solve the problems of secondary pollutants, raw materials and preparation process are not environmentally friendly, secondary pollution of solid waste, etc., to achieve the effect of increasing adsorption capacity

Active Publication Date: 2015-05-13
江苏省盐海化工有限公司
View PDF7 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The surface of the adsorbent in this method is loose and porous, rich in active groups such as amino groups, hydroxyl groups, and carboxyl groups, and can produce ion exchange, electrostatic or complex adsorption with Cr(Ⅵ), and has the advantages of low cost, simple preparation method, and good adsorption effect. , easy to control, etc., but the product after adsorption will form new solid waste and produce secondary pollutants
[0006] Chinese patent 200910312497.X discloses a method of using molecular template technology to prepare Cr ion (Cr ion) with chitosan, polyethylene glycol, etc. 6+ 、Cr 3+ ) is an adsorption resin with high selectivity and high adsorption, which is beneficial to the accurate enrichment of Cr ions, achieves the purpose of removing Cr ions and recycling, and can be used repeatedly, but the raw materials used in the preparation process of the resin such as methyl Acrylic, Cr 3+ etc. are toxic substances, which are easy to pollute the environment and cause harm to production personnel.
[0007] In summary, the methods used in the prior art for chromium removal have disadvantages such as poor selective adsorption of chromium, easy generation of solid waste after adsorption to form secondary pollution, and unenvironmental protection of raw materials and preparation processes.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Polyvinyl alcohol anion-exchange membrane and preparation method thereof
  • Polyvinyl alcohol anion-exchange membrane and preparation method thereof
  • Polyvinyl alcohol anion-exchange membrane and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0057] Example 1 Preparation of Polyvinyl Alcohol Anion Exchange Membrane

[0058] 1. Preparation of quaternized polyvinyl alcohol:

[0059] Step a1: Put 3g of polyvinyl alcohol in a three-necked bottle, add an appropriate amount of deionized water, stir and swell, then gradually raise the temperature to 90°C, fully dissolve to obtain a viscous liquid polyvinyl alcohol aqueous solution, and then gradually cool down to At 65°C, add an appropriate amount of KOH aqueous solution (the molar ratio of KOH and polyvinyl alcohol hydroxyl group is 1.4:1) for alkalization, and then slowly add an aqueous solution of 3-chloro-2-hydroxypropyltrimethylammonium chloride ( The molar ratio of 3-chloro-2-hydroxypropyltrimethylammonium chloride to polyvinyl alcohol hydroxyl was 1:1), stirred and reacted for 4 hours to obtain a yellow liquid mixture;

[0060] Step a2: Slowly pour the yellow liquid mixture into absolute ethanol to precipitate a white solid, wash the white solid repeatedly with ...

Embodiment 2

[0064] Example 2 Preparation of Polyvinyl Alcohol Anion Exchange Membrane

[0065] In this embodiment, the quaternized polyvinyl alcohol prepared in Example 1 is used to prepare a polyvinyl alcohol anion exchange membrane, and the specific method is as follows:

[0066] Step a: Add quaternized polyvinyl alcohol into deionized water, gradually heat up to 80°C after stirring and swelling, and obtain a 10wt% aqueous solution of quaternized polyvinyl alcohol after fully dissolving; at the same time, polydimethyldiallyl Ammonium chloride was added to deionized water, and magnetically stirred at normal temperature to obtain an aqueous solution of 8wt% polydimethyldiallylammonium chloride; 18.18g of the above-mentioned quaternized polyvinyl alcohol aqueous solution and 1.82g polydimethyldiene Propyl ammonium chloride aqueous solution was mixed evenly (the total weight of the mixed solution was 20g) to obtain the initial mixed solution;

[0067] Step b: Add a little 0.1mol / L hydroc...

Embodiment 3

[0069] Example 3 Preparation of Polyvinyl Alcohol Anion Exchange Membrane

[0070] In this embodiment, the quaternized polyvinyl alcohol prepared in Example 1 is used to prepare a polyvinyl alcohol anion exchange membrane, and the specific method is as follows:

[0071] Step a: Add the prepared quaternized polyvinyl alcohol into deionized water, gradually heat up to 80°C after stirring and swelling, and obtain a 10wt% aqueous solution of quaternized polyvinyl alcohol after fully dissolving; Allyl ammonium chloride was added to deionized water, and magnetically stirred at normal temperature to obtain 8wt% polydimethyldiallyl ammonium chloride aqueous solution; 16g of the above-mentioned quaternized polyvinyl alcohol aqueous solution and 4g polydimethyldiallyl The allyl ammonium chloride aqueous solution was mixed evenly (the total weight of the mixed solution was 20g) to obtain the initial mixed solution;

[0072] Step b: Add a little 0.1mol / L hydrochloric acid solution drop...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
adsorption capacityaaaaaaaaaa
adsorption capacityaaaaaaaaaa
Login to view more

Abstract

The invention provides a polyvinyl alcohol anion-exchange membrane and a preparation method thereof. The polyvinyl alcohol anion-exchange membrane is prepared from quaternary polyvinyl alcohol, polydimethyldiallylammonium chloride, tetraethoxysilane and a cross-linking agent, wherein the weight ratio of the quaternary polyvinyl alcohol to the polydimethyldiallylammonium chloride is 1: (0.1 to 0.6). The polyvinyl alcohol anion-exchange membrane prepared by the preparation method provided by the invention is good in selective adsorption and high in adsorption capacity for chromium ions, free from secondary pollution after adsorption, as well as environment-friendly in raw materials and preparation process.

Description

technical field [0001] The invention belongs to the field of chemistry, and in particular relates to a polyvinyl alcohol anion exchange membrane. Background technique [0002] Cr(Ⅵ) belongs to the first class of pollutants, its toxicity is 100 times that of Cr(Ⅲ), it has great harm to the human body, and long-term intake may cause cancer. Chromium will not degrade by itself under natural conditions, and has a persistent danger to the environment. Chromium mainly comes from processes such as electroplating, tanning, printing and dyeing, and chromium salt production. The state has strict restrictions on the wastewater discharge of the above-mentioned enterprises, and the Cr (Ⅵ) discharge standard must be lower than 0.5mg / L. [0003] Cr(Ⅵ) is one of the common toxic heavy metals, especially in electroplating wastewater and leather wastewater. At present, the methods for removing Cr reported in the literature mainly include chemical adsorption, membrane interception, electroly...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): B01D71/38B01D67/00B01J41/14C02F1/42C02F1/44C02F101/22
Inventor 董锐张建勋
Owner 江苏省盐海化工有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products