Liquid-crystal orientation agent, liquid-crystal orientation membrane and liquid-crystal display component
A liquid crystal alignment agent, polymer technology, applied in liquid crystal materials, optics, instruments, etc.
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Embodiment 1
[0142] In Examples 1, 8, and 9, the content of diamine (a-1-1) is gradually increasing, and the content of diamine (a-1-1) in Example 1 is the lowest, and its residual DC voltage is 81mV. The content of the diamine (a-1-1) in Example 9 is the highest, but its image sticking property at room temperature is the worst, and the residual DC voltage is the highest. Therefore, the amount of diamine (a-1-1) used has a certain range, and if it is not used at all as in Comparative Examples 1' and 2', or used in excess as in Examples 8 and 9, it will cause residual DC voltage of the liquid crystal display component The higher the temperature and the worse the image sticking characteristics at room temperature, the amount of diamine (a-1-1) is preferably less than 30wt% of the total amount of diamine, more preferably less than 15wt%.
[0143] In Examples 1 to 4, the diamine and tetracarboxylic dianhydride (a-4) used are the same, and the difference between the four mainly lies in the imid...
Embodiment 13
[0159] The only difference between Example 13 and Comparative Example 3' is that the latter replaces diamine (a-1-2) with diamine (a-2-1), that is, comparative example 3' only uses diamine (a- 2-1), diamine (a-3-6), but without using diamine (a-1-2), the residual DC voltage of comparative example 3' is significantly higher. Therefore, the present invention simultaneously uses three kinds of diamines as reactants of polymer (A), through the phenolic groups provided by diamines (a-1) and diamines (a-2), and the combination of phenolic groups and tertiary nitrogen atoms The synergistic effect can reduce the residual DC voltage of the liquid crystal display component.
[0160] In Examples 10, 11, 13, and 14, three kinds of diamines were used as reactants of the polymer (A), and the obtained image sticking characteristics were excellent and excellent, and the residual DC voltage was 19 to 48, which showed that the simultaneous use of diamines ( a-1-2) and diamine (a-2-1), and addi...
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