Highly heat-shrinkable polyamide fibers, and filament-mixed yarn and woven or knit fabric each including same
A polyamide fiber and shrinkage technology, applied in the direction of single-component polyamide rayon, fabric, knitting, etc., can solve the problems of high Young's modulus and hard hand feeling, and achieve the effect of excellent shrinkage characteristics
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Embodiment 1
[0116] Polycaprolactam (N6) (relative viscosity ηr: 2.62, melting point 222°C) as a crystalline polyamide and isophthalic acid / terephthalic acid as a non-crystalline polyamide at a copolymerization ratio of 7 / 3 Polycondensate of phthalic acid (6I) / terephthalic acid (6T) / hexamethylenediamine (relative viscosity ηr: 2.10), the weight ratio of crystalline polyamide / non-crystalline polyamide is 70 / 30 Melt-kneading was carried out at 265° C. using a single-screw extruder, and melt discharge was carried out using a spinneret having 26 circular discharge holes (spinning temperature: 265° C.). After being melted and discharged, the filaments are cooled, oiled, and interwoven, and then drawn with the first godet roller (stretching temperature: 150°C) at 1500m / min, and then stretched to 2.4 times and then heat-set at 165°C. A polyamide yarn of 33 dtex26 filaments (relative viscosity ηr: 2.46, glass transition temperature (Tg): 91° C.) was obtained at a winding speed of 3500 m / min.
Embodiment 2
[0118] Except that the weight ratio of crystalline polyamide / non-crystalline polyamide was 85 / 15, spinning was carried out in the same manner as in Example 1 to obtain polyamide filaments of 33 dtex26 filaments (relative viscosity ηr: 2.54, Glass transition temperature (Tg): 87°C).
Embodiment 3
[0120] Except that the weight ratio of crystalline polyamide / non-crystalline polyamide was 55 / 45, spinning was carried out in the same manner as in Example 1 to obtain polyamide filaments of 33 dtex26 filaments (relative viscosity ηr: 2.39, Glass transition temperature (Tg): 92°C).
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