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345 results about "Relative viscosity" patented technology

Relative viscosity (ηᵣₑₗ) (a synonym of "viscosity ratio") is the ratio of the viscosity of a solution (η) to the viscosity of the solvent used (ηₛ), ηᵣₑₗ=η/ηₛ.

Method for continuous production of polyamide

Provided is a continuous production method of a polyamide with stabilized polymerization degree and good quality, particularly an aromatic-containing polyamide. A continuous production method of a polyamide, comprising (a) a raw material preparation step of individually melting a diamine and a dicarboxylic acid, or producing a salt of amine and carboxylic acid in water, (b) a raw material introduction step of continuously introducing the prepared raw materials into a tubular reaction apparatus, (c) an amidation step of passing the introduced raw materials through the tubular reaction apparatus, thereby effecting amidation to obtain a reaction mixture containing an amidated product and a condensed water, (d) an initial polymerization step of introducing the reaction mixture into a continuous reaction apparatus capable of separation and removal of water, and elevating the polymerization degree while separating and removing water at a temperature higher than the melting point of the finally obtained polyamide to obtain a polyamide prepolymer, and (e) a final polymerization step of introducing the polyamide prepolymer into a continuous reaction apparatus capable of separation and removal of water, and further elevating the polymerization degree at a temperature higher than the melting point of the finally obtained polyamide to obtain a polyamide adjusted to a desired relative viscosity [RV].
Owner:TOYOBO CO LTD

Polyethylene/nylon alloy composite material and preparation method thereof

The invention discloses a polyethylene/nylon alloy composite material and a preparation method thereof. The polyethylene/nylon alloy composite material is prepared from the following components in percentage by mass: 20-90% of recycled PE/PA (polyethylene/polyamide) composite membrane, 3-20% of thermoplastic elastic body graft, 5-50% of inorganic filler, 0.1-3% of chain extender, 0.1-1% of antioxidant, 0.1-1% of coupling agent, 0.2-3% of lubricating agent and 0.5-3% of other functional auxiliaries. The recycled waste PE/PA composite membrane is taken as a main raw material, thus the waste material is changed into things of value and resource recycling is realized. The thermoplastic elastic body graft is taken as a compatilizer, compatibility of PE and PA can be obviously improved, a homogeneous system in micro morphology is formed, comprehensive performance and impact toughness of the material are improved, and balanced physical mechanical properties can be obtained. The chain extender is adopted, molecular weight and relative viscosity of nylon can be effectively improved, and the defect that the physical mechanical properties are reduced owning to breaking of a molecular chain in a nylon regenerating process can be effectively avoided. The preparation method is a one-step method, production process is simple, and processing cost is low.
Owner:GUANGZHOU SUPER DRAGON ENG PLASTICS

Method for continuous production of polyamide

Provided is a continuous production method of a polyamide with stabilized polymerization degree and good quality, particularly an aromatic-containing polyamide. A continuous production method of a polyamide, comprising (a) a raw material preparation step of individually melting a diamine and a dicarboxylic acid, or producing a salt of amine and carboxylic acid in water, (b) a raw material introduction step of continuously introducing the prepared raw materials into a tubular reaction apparatus, (c) an amidation step of passing the introduced raw materials through the tubular reaction apparatus, thereby effecting amidation to obtain a reaction mixture containing an amidated product and a condensed water, (d) an initial polymerization step of introducing the reaction mixture into a continuous reaction apparatus capable of separation and removal of water, and elevating the polymerization degree while separating and removing water at a temperature higher than the melting point of the finally obtained polyamide to obtain a polyamide prepolymer, and (e) a final polymerization step of introducing the polyamide prepolymer into a continuous reaction apparatus capable of separation and removal of water, and further elevating the polymerization degree at a temperature higher than the melting point of the finally obtained polyamide to obtain a polyamide adjusted to a desired relative viscosity [RV].
Owner:TOYO TOYOBO CO LTD

Halogen-free flame retardant continuous long glass fiber reinforced polyamide 66 composite material and preparation method thereof

The invention discloses a halogen-free flame retardant continuous long glass fiber reinforced polyamide 66 composite material which comprises the following ingredients by weight percent: 42-72.5% of polyamide 66, 2-6% of flexibilizer, 10-20% of halogen-free flame retardant, 0.5-2.0% of heat stabilizer and 15-30% of long glass fiber, wherein the relative viscosity of the polyamide 66 is 2.0-3.0; and the long glass fiber is an LFT (Long Fiber Thermoplastic) alkali-free continuous long glass fiber specially used for polyamide 66. The prepared material has high fluidity, excellent heat resistance, high rigidity, high impact, high size stability, excellent flame retardant property and high CTI (comparative tracking index) value; through detection, the tensile strength of the material is not less than 150MPa, the flexural modulus is not less than 7000MPa, the notch impact strength is not less than 15KJ/m<2>, the heat distortion temperature (1.80MPa) is not less than 250 DEG C, the flame retardant grade is UL94 1.6mmV-0, and the CTI value is not less than 500V; and moreover, the defect in halogen-free flame retardant high temperature decomposition is solved by using a technique of high-low-temperature double-melting body infiltration tank serial connection.
Owner:JIANGSU KINGFA SCI & TECH ADVANCED MATERIALS CO LTD

Halogen-free flame-retardant continuous long glass fiber reinforced polyamide 6 composite material and preparation method thereof

ActiveCN103013098AImprove performanceSolve serious defects of decompositionHeat deflection temperatureGlass fiber
The invention discloses a halogen-free flame-retardant continuous long glass fiber reinforced polyamide 6 composite material, which consists of the following components in percentage by weight: 42-72.5 percent of polyamide 6, 2-6 percent of flexibilizer, 10-20 percent of halogen-free flame retardant, 0.5-2.0 percent of heat stabilizer and 15-30 percent of long glass fiber, wherein the relative viscosity of polyamide 6 is 2.0-3.0; and the long glass fiber is an LFT alkali-free continuous long glass fiber special for polyamide 6. The material prepared by the preparation method has high liquidity, excellent heat resistance, high rigidity, high impact, high dimensional stability, excellent flame retardant property and high CTI value; and due to the detection, the tensile strength is more than or equal to 120MPa, the flexural modulus is more than or equal to 6,500MPa, the notch impact strength is more than or equal to 20KJ / M<2>, the distortion temperature (1.80MPa) is more than or equal to 200 DEG C, the flame-retardant level reaches UL94 1.6mmV-0, and the CTI value is more than or equal to 500V; and moreover, by adoption of the high / low-temperature dual-melt infiltration tank series technology, the defect that the halogen-free flame retardant is decomposed at a high temperature is overcome.
Owner:JIANGSU KINGFA SCI & TECH ADVANCED MATERIALS CO LTD

Continuous polymerization production process of high-viscosity polyamide 6

The invention relates to a continuous polymerization process of high-viscosity polyamide 6, comprising the following steps of: preparing caprolactam with de-ionized water; pre-heating the mixed caprolactam to a temperature in a range of 220+ / -30 DEG C by a pre-heater and conveying the mixed caprolactam into a pre-polymerizer by a feeding pump to carry out hydrolyzed ring opening and pre-polymerization on the caprolactam, wherein the pressure of the ring opening and the pre-polymerization is 2.50+ / -0.50 bar, the temperature is in a range of 270+ / -15 DEG C and the flow of the caprolactam is 2200+ / -500 kg / h; then, discharging materials into a post-polymerizer to carry out post-polymerization to obtain a polymer melt, wherein the pressure of the post-polymerization is 0.35+ / -0.25 bar and the temperature is 250+ / -30 DEG C; treating the polymer melt by a polymer filter, a casting strip head, an underwater granulator and a vibrating screen to obtain slices; adding the slices into a pre-extracting water pot to carry out pre-extraction with hot water at the temperature in a range of 115+ / -10 DEG C; then, conveying the treated slices into an extracting tower and extracting with the hot water at the temperature in a range of 100+ / -20 DEG C; conveying the extracted slices into a drying tower and carrying out counter-current drying by nitrogen gas; drying at the temperature in a range of 120+ / -30 DEG C and discharging the dried slices into a slice cooling bin; and conveying the cooled slices into a slice storage bin and a slice packaging bin by the nitrogen gas and packaging to obtain the high-viscosity polyamide 6 slices with the relative viscosity of 3.4-4.0.
Owner:湖南岳化化工股份有限公司

Polyamide mold composition

The invention discloses a polyamide mold composition, which consists of at least one polyamide resin, glass fiber, hydro-oleophobic master batches, a heat stabilizer and other additives, wherein the melting point of the polyamide resin is between 270 DEG C and 340 DEG C, and the relative viscosity of the polyamide resin, measured by 96 percent concentrated sulfuric acid at the temperature of 25 DEG C, is between 2.0 and 2.4. The composition is prepared by the following steps of: preparing the hydro-oleophobic master batches; extruding and pelletizing; drying and uniformly mixing the obtained hydro-oleophobic master batches with the polyamide resin, the heat stabilizer and other additives by using a high speed mixer; adding the mixture through a main feeding hole of a double screw extruder; adding the glass fiber from a second feeding hole of the extruder; and extruding and pelletizing at resin melting temperature, and drying to obtain a corresponding polyamide mold composition. The invention has the advantages that: 1, the hydro-oleophobic master batches are added into the polyamide resin, so that the physical corrosion resistance and the mechanical property of the polyamide mold composition can be enhanced; and 2, a fluorine-containing copolymer in the master batches is beneficial to the dilution and the dispersion of the fluorine-containing copolymer in the master batches during secondary processing.
Owner:KINGFA SCI & TECH CO LTD +1

Active lubricant for wear-resistant material and high-strength wear-resistant nylon material

The invention relates to an active lubricant for wear-resistant materials and a high-strength wear-resistant nylon material. The active lubricant for wear-resistant materials comprises the following substances: molybdenum disulfide, graphite and an active treating agent; and the solid-state active lubricant is prepared through feeding the substances to a high-speed mixer according to the formulation and then mixing the substances. The high-strength wear-resistant nylon material comprises the following substances: 100 parts of nylon, 6-20 parts of solid-state active lubricant, 3-6 parts of toughening agent and 1-10 parts of additive; and the high-strength wear-resistant nylon material is prepared through feeding the substances to the high-speed mixer for high-speed mixing, and then pouring the substances to an extruder. When applied in nylon resin, the active lubricant can significantly improve the friction reducing capability, wear resistance, relative viscosity and comprehensive mechanical properties of the nylon matrix material, and can also prolong the service life of the material. Meanwhile, the active lubricant integrates the functions of activation modification of the surface of the solid lubricant and chain extension of the nylon resin, and enhances the physical and mechanical properties of nylon. The preparation method is simple and convenient, has good effect and is easy to be industrialized.
Owner:HEFEI UNIV OF TECH
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