Method for tracing pollutants by combining water quality parameters with three-dimensional fluorescence spectrum

A technology of water quality parameters and three-dimensional fluorescence, applied in the field of pollutant traceability, can solve problems such as troublesome operation, heavy workload, unfavorable water pollution sources, etc., and achieve the effect of simple operation, effective identification and good reproducibility

Inactive Publication Date: 2019-03-15
EAST CHINA UNIV OF SCI & TECH
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Problems solved by technology

Fluorescence spectrum analysis generally uses the peak recognition method to determine the excitation and emission wavelengths by using the position of the maximum fluorescence intensity, and then determine the type of fluorescence peak. Compare
If there are too many samples, the workload will be huge, which is not conducive to efficient and quick judgment of the source of water pollution
The PARAFAC method is based on the three-line decomposition theory, and the "mathematical separation" of fluorescent substances can be realized by using the alternating least squares algorithm, but it can only identify the characteristic fluorescent components, and cannot define the exact source of each fluorescent component

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  • Method for tracing pollutants by combining water quality parameters with three-dimensional fluorescence spectrum
  • Method for tracing pollutants by combining water quality parameters with three-dimensional fluorescence spectrum
  • Method for tracing pollutants by combining water quality parameters with three-dimensional fluorescence spectrum

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Embodiment Construction

[0022] like figure 1 As shown, the present invention provides a method for traceability of pollutants in combination with water quality parameters and three-dimensional fluorescence spectrum, comprising the following steps:

[0023] Water quality detection steps: carry out routine water quality parameter detection on water samples, and then use PCA / FA analysis to determine the number of principal factors of conventional water quality parameters, and then use the PMF model to calculate the factor contribution rate of each conventional water quality parameter according to the number of principal factors The contribution rate determines the main pollution sources;

[0024] Fluorescence detection steps: Take 4mL of the water sample into a 10mm cuvette, use a three-dimensional fluorescence spectrum analyzer, set relevant parameters, perform three-dimensional fluorescence spectrum detection on the water sample, and then perform PARAFAC analysis on the three-dimensional fluorescence ...

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Abstract

The invention provides a method for tracing pollutants by combining water quality parameters with a three-dimensional fluorescence spectrum. The method comprises the following steps of water quality testing, fluorescence detection, pollution source type identification, and pollution source determination. The pollutant tracing method is combined with PMF model factor analysis results and the fluorescence intensity ratio of characteristic fluorescent components to quickly judge whether a water body environment is affected by human activities or not and judge the type of a water body pollution source at the same time; in addition, targeted screening of pollution sources is carried out by combining with relevant regional water quality monitoring distribution points with hydrological parameters; and finally, main pollution sources of a water body are defined by comparing test results of the corresponding pollution sources. The method has the advantages of simple operation, high accuracy, good reproducibility and the like; typical pollution sources in the water body environment can be quickly and effectively identified and theoretical guidance is provided for control and treatment of related pollution.

Description

technical field [0001] The invention relates to a method for tracing the source of pollutants, in particular to a method for tracing the source of pollutants by combining water quality parameters and three-dimensional fluorescence spectrum. Background technique [0002] With the rapid development of human society, the water body environment has been seriously polluted. The pollution is mainly divided into water quality changes caused by natural factors and water quality deterioration caused by human factors, such as the discharge of living sources, agricultural non-point source pollution, industrial wastewater discharge, etc. . In order to effectively control water body pollution, it is necessary to clarify the types and characteristics of pollution sources of water bodies, and take corresponding control and treatment measures to quickly investigate and control pollution sources and ensure water quality safety. [0003] Usually, water quality monitoring relies on chemical o...

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/64G01N33/18
CPCG01N21/64G01N33/18G01N2021/6417Y02A20/20
Inventor 刘莉莉董永成武广哲唐周陈鑫孙小淇周纯淳林森张敬赵翰斌
Owner EAST CHINA UNIV OF SCI & TECH
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