Laminated body and its manufacturing method
一种制造方法、层叠体的技术,应用在化学仪器和方法、涂层、分层产品等方向,能够解决测定对象误差、分裂和分裂的程度未知、不具有多个极大值等问题,达到优异耐候性和密合性的效果
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[0214] Synthesis examples, production examples, examples, and comparative examples are shown below to describe the present invention in detail, but the present invention is not limited to the following examples.
[0215] In addition, molecular weight is the number average molecular weight of polystyrene conversion calculated|required by GPC measurement. The viscosity is a value at 25° C. measured using a rotational viscometer.
[0216] (1) Synthesis of compounds
Synthetic example 1
[0217] [Synthesis Example 1] Synthesis of (A)-1
[0218] [chemical 9]
[0219]
[0220]Methyl Silicate 51 (manufactured by Colcoat Co. Ltd., 235 g, 0.5 mol), TBT700 (Nippon Soda ( Co., Ltd., 0.1 g), di-tert-butylhydroxytoluene (0.6 g), and heated to 85°C. Hydroxyethyl acrylate (551 g, 5 mol) was added and reacted there. Distillation of methanol (80 g) was seen. The reaction mixture was heated under reduced pressure (100° C. / 5 mmHg) for 2 hours to obtain (A)-1 as a colorless liquid (95% yield).
Synthetic example 2
[0221] [Synthesis Example 2] Synthesis of (A)-2
[0222] [chemical 10]
[0223]
[0224] Methyl Silicate 51 (manufactured by Colcoat Co. Ltd., 235 g, 0.5 mol), TBT700 (Nippon Soda ( Co., Ltd., 0.1 g), di-tert-butylhydroxytoluene (0.6 g), and heated to 85°C. Hydroxyethyl acrylate (61 g, 0.55 mol) was added and reacted there. Distillation of methanol (15 g) was seen. The reaction mixture was heated under reduced pressure (100° C. / 5 mmHg) for 2 hours to obtain (A)-2 as a colorless liquid (95% yield).
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