The invention relates to an
analysis method for quantitatively detecting trace and trace
nickel ions in
water based on an
ultraviolet visible
diffuse reflection spectrum enriched by a carboxyl
fiber membrane. The preparation method comprises the following specific steps: preparing a carboxyl modified
fiber membrane material, and preparing a
nickel nitrate solution, a
dimethylglyoxime ethanol solution and a
Tris-HCl
buffer solution reagent required by an experiment; the enrichment conditions of the carboxyl
fiber membrane on
nickel ions, namely pH and flow velocity, are optimized by adopting a variable control method, so that the optimal enrichment condition is obtained; the detection conditions of
nickel ions by adopting a variable control method: the dosage of a color developing agent
dimethylglyoxime ethanol solution and the reaction time are optimized, and the optimal detection conditions are obtained; dropwise adding a color developing agent on the film to generate a Ni < 2 + > complex, and determining the optimal absorption
wavelength point of
nickel ions through an
ultraviolet-visible
diffuse reflection spectrum; the method comprises the following steps: preparing a series of Ni < 2 + > solutions with different concentrations under the optimal enrichment condition, enriching by using a carboxyl fiber membrane, dropwise adding a color developing agent on the membrane to directly detect the
ultraviolet-visible
diffuse reflection spectrum of the membrane, and establishing a working curve of Ni < 2 + >; the method is based on fiber membrane enrichment and ultraviolet-visible diffuse
reflection spectrum technologies, does not need an
elution step, and is rapid in detection and high in accuracy. The method is suitable for quantitative analysis of trace heavy
metal ions in water.