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Method and system for reducing oxidation rate of flow battery electrodes

A technology for flow battery and electrode oxidation, applied in the direction of regenerative fuel cells, etc., can solve the problems of no substantive effect and little effect of protecting electrodes, and achieve the effect of reducing the oxidation speed, the method is safe, and the oxidation speed is slow.

Active Publication Date: 2021-10-26
DALIAN RONGKE POWER
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Problems solved by technology

[0006] The method of increasing the flow rate at the end of charging: In previous reports, the method of increasing the flow rate of the electrolyte at the end of charging was used to reduce the charging difficulties caused by the increase in concentration polarization at the end of charging, thereby slowing down the electrode oxidation. However, this method has little effect on protecting the electrodes. Minor, no substantial effect

Method used

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  • Method and system for reducing oxidation rate of flow battery electrodes
  • Method and system for reducing oxidation rate of flow battery electrodes
  • Method and system for reducing oxidation rate of flow battery electrodes

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Embodiment Construction

[0021] In this embodiment, a method for reducing the oxidation rate of the electrodes of the flow battery is to quickly determine the overall average valence state of the positive and negative electrolytes before the SOC of the positive electrolyte reaches 85%. When the overall average valence state is ≥3.6, specifically, when the SOC of the positive electrode electrolyte is greater than 85% at the end of charging, method 1 is used to reduce the oxidation speed of the positive carbon felt electrode—the method of automatically adding a reducing agent; when When the overall valence state is <3.6, specifically, when the SOC of the positive electrode electrolyte is greater than 80%, use method 2 to reduce the oxidation rate of the positive carbon felt electrode—introduce part of the negative electrode electrolyte to the positive electrode.

[0022] Among them, the calculation method of the overall average valence state of the electrolyte is as follows:

[0023] There are four vale...

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Abstract

The method and system for reducing the oxidation rate of the electrode of the flow battery belong to the field of the flow battery. In order to solve the problem of the electrode oxidation of the flow battery, the technical points are: including the step of adding an organic reducing agent to the positive electrolyte solution, and the effect is to reduce Oxidation rate of the positive carbon felt electrode.

Description

technical field [0001] The invention belongs to the field of liquid flow batteries, and relates to a method and a system for reducing the oxidation speed of electrodes of a liquid flow battery. Background technique [0002] All-vanadium redox flow battery has become the first choice for large-scale energy storage due to its advantages of high safety, long life, independent power capacity and convenient scale. However, the long-term operation stability of each component equipment of a large-scale MW vanadium battery project will be the main factor restricting the performance of vanadium batteries. Among them, the 10kW electric stack involves the series-parallel connection of several electric stacks, and each electric stack includes dozens of single cells in series, so the decline in the performance of any one of the batteries will directly affect the normal use of the entire electric stack, so How to improve the tolerance of a single battery, and then increase the stability ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M8/18
CPCH01M8/18Y02E60/50
Inventor 高新亮张华民邹毅王晓丽张涛
Owner DALIAN RONGKE POWER
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