Spinneret for preparing enhanced hollow fiber membrane, membrane preparation method and hollow fiber membrane
A spinneret and fiber membrane technology, applied in the field of hollow fiber membrane preparation, can solve the problems of difficult control of pre-coating liquid seepage, complex equipment, high cost, etc.
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Embodiment 1
[0032] refer to Figure 1-3 , the spinneret for preparing reinforced hollow fiber membranes of the present invention comprises a coating spinneret and a pre-coating device arranged on the top of the first coating spinneret, and the primary coating spinneret includes passing through the rope hole 22 successively Connected baffle plate 3 , primary distribution plate 4 , secondary distribution plate 5 and bottom plate 6 .
[0033] The pre-coating device includes a cover plate 1 and a pre-coating chamber 2 located below the cover plate 1. The bottom of the wall of the pre-coating chamber 2 is set on the baffle plate 3; The hole 8 and the air inlet hole 8 are symmetrically distributed on both sides of the rope hole 22. The inner radial direction of the air inlet hole 8 gradually becomes larger and an air inlet 11 is formed on the upper surface of the cover plate, and the air inlet 11 is connected to the air compressor. . Two atomizing holes 7 leading to the precoating chamber 2 a...
Embodiment 2
[0043] The method for preparing reinforced hollow fiber membrane using spinneret of the present invention comprises the following steps:
[0044] Support tube pretreatment: the support tube is passed through the threading hole 22 of the spinneret of the present invention, the coating liquid is supplied to the liquid inlet hole 24 by a metering pump, and the high-speed airflow is supplied to the air inlet hole 8 by an air compressor. Spinneret atomization holes 9 meet and are atomized and sprayed into the pre-coating cavity 2, evenly wetting the surface of the support tube;
[0045] Hollow fiber membrane preparation: the pretreated support tube is coated with casting solution, and then immersed in a coagulation bath for phase inversion to obtain a reinforced hollow fiber membrane.
[0046] Figure 4 It is a flow chart of the film making process of the present invention. In this embodiment, the support body is woven or knitted from polyester fiber filaments, the weaving densit...
Embodiment 3
[0054] In Example 2, the composition ratio in the coating liquid is set to PMMA:NMP=15:85, the feed rate of the coating liquid is set to 10 ml / min, the compressed air is set to 0.2MPa, except Otherwise, the operation was carried out in the same manner as in Example 2 to obtain a reinforced hollow fiber membrane 2 comprising a reinforcing layer, a coupling layer, and a separation layer connected from the inside to the outside.
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