Low viscosity precursor compositions and methods for the deposition of conductive electronic features
a technology of electronic features and precursor compositions, applied in the field of precursor compositions, can solve the problems of inadequate approaches to produce well-defined features with good electrical properties, low viscosity of formulations, and inability to use alternative deposition methods
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example 1
Comparative Example
[0321] A silver metal precursor composition containing 50 grams Ag-trifluoroacetate and 50 grams H2O was formulated. The calculated silver content of the precursor composition was 24.4 wt. % and thermogravimetric analysis showed the mass loss reached 78 wt. % at 340° C. This data corresponds to the above-described decomposition temperature for pure Ag-trifluoroacetate, within a reasonable margin for error.
example 2
Preferred Additive
[0322] A silver precursor composition was formulated containing 44 grams Ag-trifluoroacetate, 22 grams H2O, 33 grams DEGBE and 1 gram lactic acid. The calculated silver content was 21.5 wt. % and thermogravimetric analysis showed the mass loss reached 79 wt. % at 215EC. The addition of DEGBE as a conversion reaction inducing agent advantageously reduced the conversion temperature by 125EC compared to the formulation described in Example 1, a decrease of about 34 percent compared to pure Ag-trifluoracetate. The lactic acid functions as a crystallization inhibitor.
example 3
Comparative Example
[0323] A silver precursor composition was formulated containing 58 grams Ag-trifluoroacetate and 42 grams dimethylformamide. The calculated silver content was 21.5 wt. % and thermogravimetric analysis showed a mass loss of 78.5 wt. % at 335EC, a conversion temperature similar to the formulation in Example 1. This example illustrates that a common solvent (dimethylformamide) had no affect on the conversion temperature of the composition.
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