Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Low temperature crystallized nano titanium dioxide powder and sol synthesizing method

A technology of nano-titanium dioxide and sol, which is applied in the direction of titanium dioxide, titanium oxide/hydroxide, etc., can solve the problems of high equipment requirements and high production costs, achieve high photocatalytic activity, reduce equipment requirements, and effectively degrade organic matter.

Inactive Publication Date: 2009-05-06
TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
View PDF8 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because it uses corrosive titanium tetrachloride as the precursor, it requires high equipment, so the cost of industrial production is too high

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Low temperature crystallized nano titanium dioxide powder and sol synthesizing method
  • Low temperature crystallized nano titanium dioxide powder and sol synthesizing method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] Sulfuric acid with a concentration of 80% is heated to dissolve ilmenite (mass ratio ilmenite: sulfuric acid = 1:2), and the obtained solid-phase sediment is leached with water to obtain titanium liquid, and the titanium liquid is filtered to remove insoluble slag, and frozen for recrystallization The ferrous sulfate is removed by filtration to obtain a titanium-containing precursor solution; the pH value of the precursor solution is adjusted to 7 with ammonia water to obtain orthotitanic acid precipitation. Take 80g of orthotitanic acid precipitate and add 20ml of 30% hydrogen peroxide solution to dissolve, and use 30% HNO 3 Adjust pH=2, dilute the obtained solution to 200ml, and reflux at 100°C for 6 hours to obtain a yellow-orange transparent titanium dioxide nanosol.

Embodiment 2

[0052] Orthotitanic acid precipitate was obtained in the same manner as in Example 1. Take 80g of orthotitanic acid precipitate and add 20ml of 30% hydrogen peroxide solution to dissolve, adjust the pH to 0.5 with 30% nitric acid, dilute the resulting solution to 200ml with pure water, reflux at 100°C for 6 hours to obtain a milky white precipitate, and obtain nano titanium dioxide after vacuum drying Powder, XRD spectrogram measurement results confirm that it is anatase titanium dioxide crystal, see attached figure 1 .

Embodiment 3

[0054] Sulfuric acid with a concentration of 80% is heated to dissolve aluminum titanate, and the obtained solid-phase deposit is leached with water to obtain titanium liquid, the titanium liquid is filtered to remove insoluble slag, and frozen and recrystallized to filter and remove aluminum sulfate to obtain a titanium-containing precursor solution; Precipitation of orthotitanic acid is obtained by heating the precursor solution. Take 80g of orthotitanic acid precipitate and add 20ml of 30% hydrogen peroxide solution to dissolve, use 30% HCl to adjust pH=2, dilute the resulting solution to 200ml, and reflux at 100°C for 6 hours to obtain a yellow-orange transparent titanium dioxide nanosol.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
Login to View More

Abstract

The invention belongs to an organic metal oxide-TiO2 photocatalyst preparing process, especially relating a synthesizing method of low temperature-crystallizing nanometer TiO powder and sol with high catalytic activity. And it obtains n-titanic acid deposit by making alkali neutralization and dilution hydrolyzation or heating hydrolyzation on titanic solution, and implements synthesizing related system nano crystal materials with normal-pressure and low-temperature liquid phases by such a processing process of re-dispersing the deposit by oxydol. And it largely reduces the cost of raw materials and avoids using titanium tetrachloride with strong corrosivity, reducing equipment requirements.

Description

technical field [0001] The invention belongs to the preparation process of inorganic metal oxide-titanium dioxide photocatalyst, in particular to a synthesis method of low-temperature crystallized nano-titanium dioxide powder and sol with high catalytic activity. Background technique [0002] Titanium dioxide is an important inorganic chemical raw material, used as a white pigment in coatings, inks, paper, plastics, rubber, synthetic fibers and other industries; at the same time, it also has important applications in ceramics, welding electrodes, electronics, metallurgy and other industries. The synthesis of powdered titanium dioxide is generally produced by sulfuric acid method and chlorination method: the traditional sulfuric acid method has a long process for industrial production of titanium dioxide, discharges a lot of three wastes, and the obtained product has a large and uneven particle size, which is difficult to control; while chlorination The method has high requir...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C01G23/053
Inventor 只金芳吴良专
Owner TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products