Polypropylene coarse fiber for concrete and method for preparing same

A polypropylene and crude fiber technology, applied in the field of polypropylene fiber and its preparation, can solve problems such as excessive water-cement ratio, affecting fiber reinforcement and toughening effect, increasing porosity, etc., and achieves improved interface performance and good economic benefits And social benefits, improve the effect of anti-cracking

Active Publication Date: 2010-04-14
JIANGSU SOBUTE NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still certain limitations in improving the dispersion and improving the interface between fibers and substrates only by physical methods or adding hydrophilic polymers: the interface between fibers and substrates cannot be fully filled with hydration products , the presence of hydrophilic polymers will cause water film aggregation at the interface, which will cause the water-cement ratio to be too large, which will increase the porosity accordingly, thus affecting the strengthening and toughening effect of the fiber

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] Surface treatment of silicon dioxide, the method is as follows: Weigh a certain quality of nano-silicon dioxide, use deionized water to prepare a suspension with a weight concentration of 5%, disperse it in an emulsifier at a speed of 5000r / min for 30min, and transfer In the reaction kettle, stir and heat up. When the temperature reaches 70°C, add the fully hydrolyzed 15% gamma-methacrylate trimethoxysilane (KH570) aqueous solution at one time, and ensure that the KH570 The dosage is 1% of the nano silicon dioxide, and the constant temperature is reacted for 1.0 hour; the suspension is filtered and dried at low temperature for later use.

[0051] All raw materials used were dried to constant weight for later use. Add 5kg of polypropylene slices with a melt index of 8g / 10min into the high-speed mixer, and then add 0.25kg of surface-treated silicon dioxide, 5g of antioxidant 1076, and 5g of ultraviolet absorber UV327. After mixing evenly, transfer the material to the doub...

Embodiment 2

[0055] Carry out surface treatment to silicon dioxide, method is as embodiment 1.

[0056] All raw materials used were dried to constant weight for later use. Add 5kg of polypropylene slices with a melt index of 12g / 10min into the high-speed mixer, then add 0.50kg of surface-treated silicon dioxide, 7.5g of antioxidant DLTP, and 5g of ultraviolet absorber UV327, and mix them evenly. Transfer the materials to In the twin-screw extruder hopper, the set temperature of each zone of the screw is as follows:

[0057] a district

[0058] After the melt is melted, mixed with a static mixer, and filtered by a filter, it is extruded from the regular pentagonal spinneret hole of the spinneret and cooled in a water bath at 15°C. The water bath contains 3.0% conventional polypropylene spinning oil Agent 2038 (Changzhou Lingda Chemical Co., Ltd.), the fiber after leaving the water bath is drawn 5.0 times on a hot roll at 80°C, then heated in an oven, and then stretched twice on a...

Embodiment 3

[0060] Surface treatment of silica fume, the method is as follows: Weigh a certain quality of silica fume, prepare a suspension with a weight concentration of 5% with deionized water, disperse it in an emulsifier at a speed of 6000r / min for 30 minutes, and transfer it to the reaction kettle , stir and heat up, when the temperature reaches 70°C, add the fully hydrolyzed 15% gamma-methacrylic propyltrimethoxysilane (KH570) aqueous solution at one time, and ensure that the amount of KH570 is 2% of silica fume, react at constant temperature for 1.0 hour; filter the suspension and dry it at low temperature for later use.

[0061] All raw materials used were dried to constant weight for later use. Put 5kg of polypropylene slices with a melt index of 15g / 10min into the high-speed mixer, then add 0.15kg of polypropylene white masterbatch, 0.20kg of surface-treated silica fume, 10.0g of antioxidant DLTP, and 7.5g of ultraviolet absorber UV327 After mixing evenly, the material is trans...

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Abstract

The invention relates to concrete used polypropylene coarse fiber and a preparation method thereof. The diameter or the equivalent diameter of a filament ranges from 0.08mm to 1.5mm with the corresponding titer of 40 to 14200 deniers, the fracture strength of more than 450MPa, the elastic modulus of more than 5000MPa and the breaking elongation of 10 percent to 30 percent. In the preparation method, polypropylene and the components of the polypropylene coarse fiber are dried to the extent that the weight is kept constant before the polypropylene and the components are mixed uniformly; after the mixture is extruded by the spinning die of a double screw extruder, the mixture is cooled in a water bath; subsequently, the mixture is graded and stretched for a plurality of times at the temperature higher than the glass transition temperature of polypropylene; on completion of the stretching, ordinary polypropylene spinning used oil solutions with the weight concentration of 5.0 percent are applied on coarse fiber bundles for thermoforming before the surface of the fiber is indented; finally, the fiber is cut and packaged according to required length. By adopting the concrete used polypropylene coarse fiber, the interface of the course fiber and a basal body has good acting force, thus improving the anti-cracking, the impermeability, the fold resistance, the toughness, the shock resistance, the freeze and melt resistance, the fire resistance, and the blast resistance of coarse fiber reinforced concrete.

Description

technical field [0001] The invention relates to a polypropylene fiber and a preparation method thereof, in particular to a polypropylene crude fiber for concrete and a preparation method thereof. Background technique [0002] Concrete is a widely used and very important building material, and is currently developing in the direction of high performance, functionality, and high durability. However, the inherent disadvantages of concrete, such as low tensile strength, high brittleness, poor toughness, and poor resistance to deformation, restrict its development and application. In recent decades, the use of synthetic fibers to strengthen concrete can achieve the purpose of improving its anti-crack and anti-seepage performance, optimizing mechanical properties, and improving freeze-thaw resistance. [0003] Synthetic fibers have been widely used in concrete. Due to the reduction or elimination of cracks, the integrity of the mortar concrete structure is maintained, and its dur...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B16/06
Inventor 缪昌文刘加平阳知乾吕进
Owner JIANGSU SOBUTE NEW MATERIALS
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