Fully biodegradable multifunctional mulch film and preparation method thereof
A biodegradable and multifunctional technology, applied in the field of multifunctional plastic film, can solve the problems of no slow release function, increased cost, poor compatibility, etc.
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Embodiment 1
[0054] Example 1: Preparation of co-plasticizer glyceryl malate (DGMA)
[0055] Put 3.0kg of malic acid and 4.0kg of glycerin in a 10L reactor equipped with a water separator, and pass N 2 Stir and react at 130-140°C for 15 hours, separate out the produced water, stop the reaction when the acid value is less than 3%, and obtain a colorless and transparent viscous liquid DGMA.
Embodiment 2
[0056] Example 2: Preparation of compatibilizer polyglyceryl sebacate (PGS)
[0057] 4.12kg sebacic acid, 1.84kg glycerin are placed in the 10L reactor that water separator is equipped with, logical N 2 Stir and react at 140-160° C. for 24 hours, and react under vacuum for 8 hours to obtain a PGS resin with a number average molecular weight of 10,200, a weight average molecular weight of 44,000, and a dispersion degree of 4.31.
Embodiment 3
[0059] Corn starch 7.0kg, urea 4.0kg, DGMA 0.5kg prepared in Example 1, glycerin 0.5kg, PGS 1.0kg prepared in Example 2, potassium dihydrogen phosphate (100 mesh) 1.0kg, oleic acid amide 0.1kg, PBAT6 .0kg, PBS6.0kg mixed evenly, blended and extruded in ZSK-58 twin-screw extruder (L / D=48), the temperature of each zone is 100°C / 140°C / 165°C / 180°C / 165°C / 150°C, Remove water by vacuum, extrude, cool with water, dry, and pelletize to obtain starch-based resin containing nitrogen, phosphorus and potassium nutrients. The obtained particles are processed into a film with a film blowing equipment with a 65mm die opening, and the film blowing machine L / D=30. The temperature in each zone is 90°C / 120°C / 135°C / 150°C / 150°C, the obtained film thickness is 0.010mm, the starch phase is evenly distributed, the processability and film-forming performance are good, the tensile strength is 18MPa, and the elongation is 370%. Each kilogram of film contains: nitrogen (calculated as urea) 15.5%; phospho...
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