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A method for detecting exogenously added ethyl hexanoate in liquor

A technology of ethyl caproate and liquor, which is applied in the direction of testing beverages, testing food, material inspection products, etc., can solve the problems of high operation and maintenance costs, achieve the effect of protecting intellectual property rights and consumer interests, and standardizing development

Active Publication Date: 2018-07-24
CHINA NAT RES INST OF FOOD & FERMENTATION IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there are also reports on the application of stable isotope technology in the liquor industry to identify the authenticity of products (such as paper: Isotope identification technology for solid-state liquor and solid-liquid liquor; patent: a method for identifying the authenticity of solid-state liquor), but the above-mentioned The research is mainly aimed at the detection of edible alcohol in liquor, but there is no discussion on whether liquor contains exogenously added ethyl caproate and other food additives, and domestic related research is still assisted by relevant databases for identification, operation and high maintenance cost

Method used

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  • A method for detecting exogenously added ethyl hexanoate in liquor
  • A method for detecting exogenously added ethyl hexanoate in liquor
  • A method for detecting exogenously added ethyl hexanoate in liquor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] a) Obtained 11 samples of newly distilled base liquor of Luzhou-flavor liquor from a traditional solid-state craft liquor enterprise, as real samples without adding ethyl caproate;

[0020] b) Purchase 4 liquor samples from the market that claim to have no exogenous ethyl caproate added;

[0021] c) Determination of the delta of ethyl hexanoate of real samples 13 C value (denoted as δ 13 C 己 );

[0022] d) Select n-propanol as the carbon isotope endogenous marker of ethyl hexanoate, and measure the δ of n-propanol in real samples 13 C value, denoted as δ 13 C 正丙醇 .

[0023] e) Calculate the difference between the carbon isotope ratio and the standard deviation of the difference between ethyl caproate and n-propanol respectively (see Table 1), it can be seen that ethyl caproate and n-propanol δ 13 The distribution range of C difference is -8.86‰~-10.55‰;

[0024] Table 1 Liquor samples without ethyl hexanoate Δ 13 C descriptive statistics

[0025]

[0026] f...

Embodiment 2

[0031] A) select the new distilled base wine sample A that does not add ethyl caproate as reference sample;

[0032] B) the food additive ethyl caproate was added in the sample A according to the ratios of 1:9, 2:8, 4:6, 6:4 and 8:2, and 5 new craft liquors were blended;

[0033] C) Determination of the δ of n-propanol and ethyl acetate of sample A and 5 new craft liquors 13 C value, calculate the difference between the carbon isotopes of ethyl hexanoate and n-propanol Δ 13 C, the results are shown in Table 3.

[0034] Table 3 Sample Descriptive Statistics

[0035]

[0036] It can be seen from Table 3 that the carbon isotope difference Δ between ethyl caproate and n-propanol in the new craft liquor 13 C decreases with the increase of ethyl hexanoate content, and when the addition of ethyl hexanoate exceeds 20%, the carbon isotope difference between ethyl hexanoate and n-propanol in the sample Δ 13 C deviates from the Δ of the liquor without adding ethyl hexanoate 13 C di...

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Abstract

The invention relates to a method for detecting exogenously added ethyl caproate in liquor based on stable isotope technology and principles, and belongs to the technical field of authenticity identification of liquor. The main steps are as follows: (1) measure the carbon isotope composition of the target compound (ethyl hexanoate) in a real liquor sample of a certain flavor, measure the carbon isotope composition of the carbon isotope endogenous marker of the target compound, and determine the target compound and The average difference and standard deviation (σ) of the δ13C values ​​between the internal standards; (2) measure the δ13C values ​​of the target compound and its endogenous markers in the liquor samples to be tested, and calculate the difference between the two Δ13C samples to be tested; ( 3) Determine whether the sample to be tested contains ethyl hexanoate added from an external source. The invention utilizes the stable isotope technology to establish a method capable of accurately detecting whether the liquor contains ethyl hexanoate added from an external source.

Description

Technical field: [0001] The invention relates to a method for identifying the authenticity of liquor based on stable isotope technology, and belongs to the technical field of authenticity identification of liquor products. Background technique: [0002] Baijiu is a unique distilled liquor product in China. It is listed as the world's six famous distilled liquors together with brandy, Scotch whiskey, vodka, rum and gin. Liquor is a traditional product with a long history of the Chinese nation, and it is also an indispensable drink with profound historical and cultural heritage to meet people's continuous progress in material culture and spiritual culture. At present, the liquor industry has become an important part of my country's food industry: in 2014, the cumulative output of my country's liquor industry was 12.5713 million tons, the annual sales revenue of the liquor industry was 525.9 billion yuan, and the total profit was 69.9 billion yuan. [0003] According to GB / T 1...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N33/14
Inventor 钟其顶王道兵
Owner CHINA NAT RES INST OF FOOD & FERMENTATION IND CO LTD
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