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Permanent magnetic material and preparation method of permanent magnetic material

A technology of permanent magnet material and permanent magnet powder, applied in the direction of magnetic materials, magnetic objects, electrical components, etc., can solve the problem of low saturation magnetization of permanent magnet materials, dispersion of magnetic moment orientation of permanent magnet materials, and low coercivity of permanent magnet materials. And other issues

Active Publication Date: 2017-08-25
GRIREM ADVANCED MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, conventionally prepared Sm 5 Fe 17 The method of permanent magnetic materials can only prepare amorphous Sm by rapid quenching 5 Fe 17 Permanent magnetic powder, then the amorphous Sm 5 Fe 17 The permanent magnet powder is heat-treated (sintered) to prepare magnetic powder, and then bonded with a binder to prepare block-shaped Sm 5 Fe 17 permanent magnet material
[0005] However, since Sm 5 Fe 17 Fe content in permanent magnet materials is less, resulting in Sm 5 Fe 17 The saturation magnetization of permanent magnet materials is low
At the same time, Sm 5 Fe 17 The main crystal phase of the permanent magnet material is the metastable Sm 5 Fe 17 phase, the Sm 5 Fe 17 It is easy to decompose at high temperature, so it is difficult to prepare dense sintered magnets by traditional sintering process
However, the grains of the Sm5Fe17 permanent magnet material prepared by the traditional rapid quenching method are isotropic (that is, the grains have no orientation), so that the formed Sm 5 Fe 17 The magnetic moment orientation of the permanent magnet material is scattered, which eventually leads to Sm 5 Fe 17 The coercive force of permanent magnet materials is low

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preparation example Construction

[0033] According to another aspect of the present invention, a kind of preparation method of permanent magnetic material is provided, and this preparation method comprises the following steps: prepare the permanent magnetic powder of amorphous state, the main component of amorphous phase permanent magnetic powder is Sm x Fe (1-x-y) m y , wherein M is selected from any one or more of Ti, V, Mo and Co, the range of x is 40-50 wt%, and the range of y is 0-5 wt%; the amorphous permanent magnet powder is heat-treated to Forming crystalline permanent magnet powder; and subjecting the crystalline permanent magnet powder to hot pressing deformation to form a permanent magnet material with anisotropic flaky grains, and the size of the flaky grains in the width direction is 20-20 80nm, the size of the length direction of the flaky crystal grains is 50-300nm.

[0034] An exemplary embodiment of a method for preparing a permanent magnetic material provided according to the present inven...

Embodiment s1 to s10

[0044] The compositions and structures of the permanent magnet materials provided in Examples s1 to s10 are shown in Table 1, and the specific process parameters for preparing the permanent magnet materials are shown in Table 2. The steps of the preparation method of the permanent magnet material are specifically described below:

[0045] First, smelting and rapid quenching are carried out according to a certain composition ratio (as shown in Table 1). The rapid quenching process is carried out under an Ar protective atmosphere, and the injection pressure is 50kPa. On the roller, amorphous permanent magnet powder is obtained after rapid quenching;

[0046] Then, the amorphous permanent magnet powder is heat-treated to the main crystal phase Sm 5 Fe 17 Precipitate to obtain crystalline permanent magnet powder;

[0047] Next, put the crystalline permanent magnet powder into the hot-pressing mold, put the hot-pressing mold into the vacuum hot-pressing equipment, and keep the v...

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Abstract

The invention provides a permanent magnet material and a preparation method of the permanent magnet material to improve the saturation magnetization and high coercive force of the permanent magnet material. Wherein, the main component of the permanent magnet material is SmxFe(1-x-y)My, wherein M is selected from any one or more of Ti, V, Mo and Co, the range of x is 40-50wt%, and y The range of 0 ~ 5wt%; the crystal grains of the permanent magnet material are anisotropic flaky grains, and the dimension of the width direction of the flaky grains is 20 ~ 80nm, and the dimension of the length direction of the flaky grains is 50 ~300nm. Since the grains of the permanent magnet material are anisotropic flaky grains, the saturation magnetization of the permanent magnet material is increased. At the same time, since the size of the plate-like crystal grains in the width direction is 20-80 nm, and the size of the plate-like crystal grains in the length direction is 50-300 nm, the coercive force of the permanent magnet material is improved.

Description

technical field [0001] The invention relates to the technical field of permanent magnet materials, in particular to a permanent magnet material and a method for preparing the permanent magnet material. Background technique [0002] In recent years, permanent magnet materials represented by rare earth permanent magnet materials have developed very rapidly. Since the discovery of the first generation of rare earth permanent magnet materials in the 1960s, SmCo has been developed successively. 5 、Sm 2 co 17 and Nd 2 Fe 14 B and other third-generation rare earth permanent magnets, and the maximum energy product representing the performance of rare earth permanent magnets has been increased from 20MGOe to 59.6MGOe. The process of preparing rare earth permanent magnets generally includes the traditional powder metallurgy process for preparing sintered rare earth permanent magnets and the melt rapid quenching process for preparing bonded rare earth permanent magnets. Among the...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01F1/047C22C45/00
Inventor 罗阳李红卫于敦波李扩社闫文龙毛永军杨远飞谢佳君
Owner GRIREM ADVANCED MATERIALS CO LTD
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