Solvent system for producing hydrogen peroxide working liquid by anthraquinone method and use thereof
A working fluid, anthraquinone method technology, applied in peroxide/peroxyhydrate/peroxyacid/superoxide/ozonide, chemical instruments and methods, inorganic chemistry, etc. Large, complex synthesis process and other problems, to achieve the effect of improving hydrogen efficiency, improving solubility, and improving production capacity
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Embodiment 1
[0019] Using heavy aromatic hydrocarbons: trioctyl phosphate: 2-phenylethyl alcohol: ethyl ether = 70:20:9:1 (volume ratio) as the working fluid medium, the solubility of 2-ethylanthraquinone is 170 g / L. The hydrogenation temperature is 50°C, the hydrogenation pressure is 0.25MPa, and the space velocity is 5h -1 , The ratio of hydrogen to liquid is 12:1. The oxidation temperature is 50°C, and the oxidation pressure is 0.20MPa. Hydrogen efficiency is 10.24 g / L
Embodiment 2
[0021] With heavy aromatics: trioctyl phosphate: 2-phenylethyl alcohol = 75:19:5:1 (volume ratio) as the working fluid medium, the solubility of 2-ethylanthraquinone is 150 g / L. The hydrogenation temperature is 55°C, the hydrogenation pressure is 0.30MPa, and the space velocity is 5h -1 , The ratio of hydrogen to liquid is 10:1. The oxidation temperature is 55°C, and the oxidation pressure is 0.20MPa. The hydrogen efficiency is 8.78 g / l.
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Abstract
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