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A kind of modified environment-friendly water-based anticorrosion paint and preparation method thereof

An anti-corrosion coating and environmental protection technology, applied in anti-corrosion coatings, coatings and other directions, can solve the problems of large amount of environmental protection anti-rust pigments, poor anti-corrosion performance, and lack of long-term anti-corrosion performance.

Active Publication Date: 2020-11-17
GUANGZHOU JOINTAS CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But this water-based industrial anticorrosion coating also has the following disadvantages: the anticorrosion performance of the coating is given by adding antirust pigments such as zinc phosphate, aluminum tripolyphosphate, iron titanium powder, although what is added is an environmentally friendly antirust pigment that does not contain heavy metal salts, but Since the anti-corrosion performance of environmentally friendly anti-rust pigments is poorer than that of anti-rust pigments containing heavy metal salts, the amount of environmentally friendly anti-rust pigments used is relatively large, which also greatly increases the manufacturing cost of coatings, which is not conducive to the development and application of coatings.
But this invention also has the following disadvantages: the test results disclosed in the example part of the description show that the corrosion inhibitor has excellent performance in the flash rust test, which can reach 0%, but it has been operated for 24 hours under the test conditions of 35 ° C and 5% saline solution In the salt spray test, the worst reaches 70%, and the best reaches 0.03%. At 35°C, 100% relative humidity, the worst reaches 33%, and the best reaches 0% in the QCT test of 200 hours of operation, which shows that the invention Long-term anti-corrosion performance is still lacking

Method used

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  • A kind of modified environment-friendly water-based anticorrosion paint and preparation method thereof
  • A kind of modified environment-friendly water-based anticorrosion paint and preparation method thereof
  • A kind of modified environment-friendly water-based anticorrosion paint and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A modified environment-friendly water-based anti-corrosion coating comprises the following components: water-based emulsion, pigments and fillers, water-based additives, organic compound modifiers and water. Wherein the aqueous emulsion is a styrene-acrylic emulsion, the hydrated particle size of the aqueous emulsion is 300nm, the solid content is 40wt%, the minimum film-forming temperature is 30°C, and the glass transition temperature is 25°C. The organic compound modifier is 142DA from Ascodi, France. The amino group and phosphonic acid group in the organic compound modifier are strong polar groups, which are easy to complex with other components such as substrates, pigments and fillers, and film-forming substances to form chemical bonds, thereby firmly adsorbing on substrates, pigments, etc. The surface of other components such as fillers and film-forming substances improves the adhesion of the coating film; compared with inorganic anti-rust pigments, the organic com...

Embodiment 2

[0044] The difference between the modified environment-friendly water-based anticorrosion coating in Example 2 and Example 1 is that the organic compound modifier is 143 from Ascodi, France.

[0045] The pigments and fillers include common commercial 2500 mesh iron yellow.

[0046] The wetting and dispersing agent is Tego 750W from Germany.

[0047] The defoamer is BYK022 from German BYK Chemicals.

[0048] The pH regulator is triethanolamine.

[0049] The co-solvent is the PM of Dow Huaxue.

[0050] The difference between the preparation method of the modified environment-friendly water-based anti-corrosion paint of Example 2 and Example 1 is that the stirring speed in the step (1) is 700r / min, and the stirring time is 8min.

[0051] The grinding time in the step (2) is 26min.

[0052] In the step (3), the stirring speed is 1100r / min, and the stirring time is 13min.

[0053] In the step (4), the stirring speed is 600r / min, and the stirring time is 8min.

[0054] In the ...

Embodiment 3

[0056] The difference between the modified environment-friendly water-based anticorrosion coating in Example 3 and Example 1 is that the organic compound modifier is 144DA from Ascodi, France.

[0057] The pigments and fillers include common commercial 2500 mesh iron black.

[0058] The wetting and dispersing agent is Tego 755W from Germany.

[0059] The defoaming agent is BYK024 from German BYK Chemicals.

[0060] The pH regulator is diethanolamine.

[0061] The co-solvent is DPNP of Dow Huaxue.

[0062] The difference between the preparation method of the modified environment-friendly water-based anti-corrosion paint of embodiment 3 and embodiment 1 is that: in the step (1), the stirring speed is 900r / min, and the stirring time is 12min.

[0063] The grinding time in the step (2) is 37min.

[0064] In the step (3), the stirring speed is 1200r / min, and the stirring time is 15min.

[0065] In the step (4), the stirring speed is 650r / min, and the stirring time is 10min.

...

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Abstract

The invention relates to a modified environment-friendly water-based anti-corrosion coating and a preparation method thereof, belonging to the field of water-based acrylic anti-corrosion coatings, comprising the following components: water-based emulsion and an organic compound modifier, wherein the organic compound modifier is an organic amine, an organic amine at least one of derivatives, organophosphine and organophosphine derivatives. The present invention forms chemical bonds with other components such as substrates, pigments and fillers, and film-forming substances through the strong polar groups in the organic compound modifier, thereby realizing multiple modifications to substrates, pigments and fillers, and film-forming substances. Not only has the slow-release and passivation effect of inorganic anti-rust pigments, but also has the shielding effect that inorganic anti-rust pigments do not have. It has long-term multiple anti-corrosion functions. Hours without blistering and rusting, the best resistance to salt water can reach more than 600 hours without blistering and rusting.

Description

technical field [0001] The invention relates to a modified environment-friendly water-based anti-corrosion coating and a preparation method thereof, belonging to the field of water-based anti-corrosion coatings. Background technique [0002] At present, the anti-corrosion coatings used in China are mainly solvent-based coatings. Although this coating has good film-forming performance and good anti-corrosion performance, because it contains organic solvents, it not only has high VOC, pollutes the atmosphere, consumes more petrochemical energy, and also has fire hazards. Risk of explosion, even endangering human health. However, water-based coatings use water as a solvent, which is not only easy to obtain, low in cost, non-flammable, not harmful to human health, and easy to realize automatic coating. Therefore, in recent years, water-based environmentally friendly coatings have become the promotion direction of the country. [0003] Chinese invention patent specification CN10...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D125/14C09D5/08C09D7/61
CPCC08K2003/2241C08K2003/2272C08K2003/3045C09D5/08C09D7/61C09D125/14C08K5/49C08K3/22
Inventor 刘瑞清张鸿张博晓余飞
Owner GUANGZHOU JOINTAS CHEM
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