Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Inorganic-organic hybrid material, preparation method and application of polyacid-based silver complex

A technology of silver complexes and organic hybridization, applied in the directions of botanical equipment and methods, chemical instruments and methods, organic compounds/hydrides/coordination complex catalysts, etc., to achieve the effect of a simple preparation process

Active Publication Date: 2021-07-16
JILIN INST OF CHEM TECH
View PDF0 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

So far, no literature has reported that in situ decarboxylation of organic ligands occurred during the hydrothermal synthesis of polyacid-based inorganic-organic hybrid materials in the presence of silver ions, and the research on hydrothermal in situ decarboxylation of great significance

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Inorganic-organic hybrid material, preparation method and application of polyacid-based silver complex
  • Inorganic-organic hybrid material, preparation method and application of polyacid-based silver complex
  • Inorganic-organic hybrid material, preparation method and application of polyacid-based silver complex

Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0031] In order to make the object, technical solution and advantages of the present invention more clear, the present invention will be further described in detail below in conjunction with the examples. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention.

[0032] Aiming at the problems existing in the prior art, the present invention provides an inorganic-organic hybrid material of a polyacid-based silver complex, its preparation method and application. The present invention will be described in detail below in conjunction with the accompanying drawings.

[0033] The molecular formula of the inorganic-organic hybrid material of the multi-acid-based silver complex provided by the embodiments of the present invention is that the molecular formula is [Ag(C 8 h 8 N 3 )(Mo 3 o 10 )], its molecular weight 701.86, monoclinic crystal system, P2 1 / m space group.

[0034] Its st...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention belongs to the technical field of macromolecular compounds, and discloses an inorganic-organic hybrid material of a polyacid-based silver complex, a preparation method and application thereof, and the molecular formula is [Ag(C 8 h 8 N 3 )(Mo 3 o 10 )]. Organic ligand 2-(pyridine-3-yl)-1H-imidazole (C 8 h 8 N 3 ) is 2-(pyridine-3-yl)-1H-imidazole-4,5-dicarboxylic acid (C 10 h 7 N 3 o 4 ) obtained by in situ decarboxylation. Ag + The one-dimensional isopolyacid (Mo 3 o 10 ) 2‑ The chain structure is connected to form a two-dimensional inorganic layered structure, and the protonated organic ligand 2-(pyridine-3-yl)-1H-imidazole and Ag + Coordination, located on both sides of the inorganic layered structure; the adjacent layered structure forms a three-dimensional supramolecular network structure through the π...π stacking force between the organic ligands between the layers. The preparation process of the invention is simple, the synthetic raw materials are cheap and easy to obtain, and the reaction conditions are mild.

Description

technical field [0001] The invention belongs to the technical field of polymer compounds, and in particular relates to an inorganic-organic hybrid material of a polyacid-based silver complex, a preparation method and an application thereof. Background technique [0002] Polyoxometalates (polyacids) are a class of polynuclear metal oxides. From the structural point of view, polyacids have a large number of oxygen atoms, large anion clusters, and the metal center is usually in the highest oxidation state. From the perspective of physical and chemical properties, polyacids have both oxidation and reduction properties, high thermal stability and adjustable structure, so they can be used in catalysis, medicine, optics and other fields. Inorganic-organic hybrid materials based on polymolybdates have attracted extensive attention from researchers because of their structural diversity and excellent performance. Although there have been some studies on [Mo 3 o 10 ] 2- Inorganic-o...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08G83/00C09K11/06B01J31/22A01N59/16A01P1/00C02F1/30C02F101/30
CPCA01N59/16B01J31/1691B01J2531/0241B01J2531/0297B01J2531/17C02F1/30C02F2101/308C02F2305/10C08G83/008C09K11/06C09K2211/188
Inventor 于晓洋罗亚楠曲小姝杨艳艳曹雪玲陈哲杨莹
Owner JILIN INST OF CHEM TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com