The invention discloses a method for preparing micro-capsulized superfine red phosphorus, boiling the superfine red phosphorus with vitriol, sodium cyanide solution and sodium hydroxide solution, separately, filtering, eliminating impurities, and drying, and storing by sealing; blending and dissolve metal compound, depositing with ammonia, centrifuging and adding water to dilute, raising temperature, dropping in aluminum nitrate, vitriol or HCl and making metal hydroxide sol; mixing propylene acylamide monomers and N, Ní»-methylene dipropylene acylamide with ammonium persulphate, raising temperature and reacting to form high molecular network gel; adding the high molecular network gel into the metal hydroxide sol, raising the temperature and reacting to form high molecular network gel of metal hydroxide, mixing the high molecular network gel of metal hydroxide with the processed superfine red phosphorus, blending and placing still so that the sol takes the red phosphorus as the center to make surface absorption to form gel and coating a layer of colloid membrane on the red phosphorus surface, so as to obtain the micro-capsulized superfine red phosphorus. The advantages of the invention: it improves the stability, invariability and surface activity of the red phosphorus, improving processing property.