Proportion optimization method of phosphogypsum-based solid waste filling material to improve filling rate

An optimization method, phosphogypsum technology, applied in chemical statistics, chemical machine learning, chemical data mining, etc., can solve volume instability, reduce the economic benefits of filling mining, increase the cost of filling mining, etc., to achieve cost reduction, Realize the effect of large-scale and high value-added utilization

Active Publication Date: 2020-07-24
UNIV OF SCI & TECH BEIJING +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the poor gelation and volume instability caused by the harmful mineral components in phosphogypsum, the current utilization rate of phosphogypsum is less than 5%, and most of the phosphogypsum is stacked.
[0008] To sum up, the current method to improve the filling stope roofing rate involves many types of filling materials, complex preparation processes, and manual intervention with supporting excavation engineering.
It not only increases the cost of filling mining, but also complicates the mining and filling process and procedures, thereby prolonging the mining and filling cycle, thereby reducing the production capacity of filling mining, thereby reducing the economic benefits of filling mining

Method used

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  • Proportion optimization method of phosphogypsum-based solid waste filling material to improve filling rate
  • Proportion optimization method of phosphogypsum-based solid waste filling material to improve filling rate
  • Proportion optimization method of phosphogypsum-based solid waste filling material to improve filling rate

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0061] A method for optimizing the ratio of phosphogypsum-based all-solid waste filling materials in a phosphogypsum-slag-carbide slag system comprises the following steps:

[0062] Drying and grinding of phosphogypsum solid waste, as well as mineral composition analysis and particle size testing.

[0063] The results of mineral composition analysis of phosphogypsum in the filler of phosphogypsum-slag-carbide slag system are shown in Table 1. Particle size gradation distribution curve see figure 1 .

[0064] Table 1: Mineral composition analysis results of phosphogypsum solid waste

[0065] Mineral composition P 2 o 5

Fe 2 o 3

Al 2 o 3

MgO CaO SO 4 2-

F acid insoluble matter content / % 1.47 0.48 0.36 2.44 28.6 49.07 0.87 10.17

[0066] The particle size distribution curve of slag fine powder in the filler of phosphogypsum-slag-carbide slag system is shown in figure 2 , it can be seen that the content of -45μm ...

Embodiment 2

[0087] A method for optimizing the ratio of phosphogypsum-based solid waste filling materials in the system of phosphogypsum-slag-carbide slag-iron separation slag comprises the following steps:

[0088] Drying, grinding, mineral composition analysis and particle size testing of phosphogypsum solid waste.

[0089] The mineral composition of phosphogypsum in the filler of the phosphogypsum-slag-carbide slag-iron separation tailings system is shown in Table 4.

[0090] Table 4: Phosphogypsum mineral composition of phosphogypsum-slag-carbide slag-iron separation tailings system

[0091] Mineral composition P 2 o 5

Fe 2 o 3

Al 2 o 3

MgO CaO SO 4 2-

F acid insoluble matter content / % 1.76 0.48 0.28 2.44 30.64 53.52 0.45 6.67

[0092] See figure 2 , slag micropowder -45μm fine particle content accounted for 81.9%;

[0093] The mineral composition of slag is shown in Table 5, and the quality factor of slag is Acti...

Embodiment 3

[0114] A method for optimizing the filling ratio of phosphogypsum-slag-carbide slag-fly ash system comprises the following steps:

[0115] Drying, grinding, mineral composition analysis and particle size testing of phosphogypsum solid waste.

[0116] The mineral composition of phosphogypsum in the filling material of phosphogypsum-slag-carbide slag-fly ash system is shown in Table 7.

[0117] Table 7: Mineral composition of phosphogypsum in phosphogypsum-slag-carbide slag-fly ash system

[0118] Mineral composition P 2 o 5

Fe 2 o 3

Al 2 o 3

MgO CaO SO 4 2-

F acid insoluble matter content / % 1.76 0.48 0.28 2.44 30.64 53.52 0.45 6.67

[0119] The particle size distribution curve of slag fine powder of phosphogypsum-slag-carbide slag-fly ash system figure 2 , slag micropowder-45μm fine particle content is 81.9%;

[0120] The mineral composition of slag is shown in Table 8, slag mass coefficient, activity coeffic...

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Abstract

The invention provides a proportion optimizing method of a phosphogypsum-based all-solid waste filler for improving a roof-contacted filling rate, and belongs to the technical field of environment-friendly filling mining. The method comprises the following steps: firstly performing mineral analysis and a particle size test on phosphogypsum and low-quality solid waste; performing a strength test and an expansion rate test on a filling body with different proportions of the phosphogypsum-based all-solid waste filler; establishing a strength and expansion rate mathematical model of the filling body based on the test results; establishing a proportion optimization model of the a phosphogypsum-based all-solid waste filler; and finally solving the proportion optimization model to obtain an optimized proportion of the phosphogypsum-based all-solid waste filler. The method makes full use of the self expandability of the phosphogypsum, realizes the proportion optimal combination and synergy ofmultiple low-quality solid waste, can avoid deterioration of the strength of the filling body caused by excessive expansion of the filling body, and can make the swellability of the phosphogypsum exerted to the utmost extent on the basis of meeting the strength of the filling body, thereby improving the roof-contacted filling rate of filling stope.

Description

technical field [0001] The invention relates to the technical field of green filling and mining, in particular to a method for optimizing the ratio of phosphogypsum-based all-solid waste filling materials to improve the filling rate. Background technique [0002] With the rapid development of my country's national economy and the continuous development and utilization of mineral resources, high-grade resources with good mining technical conditions are increasingly exhausted, and more mining resources are faced with deep burial, high stress, flooding and unfavorable conditions. For safety, environmental protection and green mining, the filling and filling mining method is the primary choice for resource mining at present. The full tailings cemented filling body with cement as the cementitious material has low strength and poor slurry fluidity, resulting in a large amount of filling cementitious material and high filling mining costs. At the same time, the viscosity of the fu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/14G16C20/70
CPCC04B28/143C04B2111/00724G16C20/70C04B18/141C04B22/064C04B18/144C04B18/08
Inventor 杨晓炳温震江吴凡高谦黄笃学闫满志郭斌陈彦亭胡亚军涂光富
Owner UNIV OF SCI & TECH BEIJING
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