A kind of zif-8/non-woven composite material and preparation method thereof
A technology of ZIF-8 and composite materials, which is applied in the direction of non-woven fabrics, textiles, papermaking, fiber types, etc., can solve the problems of high energy consumption, large equipment footprint, complex preparation process, etc., and achieve low energy consumption and low cost. The effect of low cost and simple process
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[0060] The ZIF-8 / nonwoven fabric composite material obtained by the preparation method of the present invention has excellent hydrophobic and lipophilic properties, for example, the contact angle of the obtained composite material is greater than 120°, preferably above 125°, and even reaches 137.5°. The oil absorption of the obtained composite material, that is, the oil absorption per gram of the non-woven fabric, is 30-37 g / g.
[0061] The preparation method provided by the present invention can control the loading of ZIF-8 nanoparticles on the non-woven fabric by controlling the amount of ZIF-8 original solution and the time of in-situ deposition, and then control the performance of the obtained composite material; the present invention adopts the original The ZIF-8 / non-woven fabric composite material is prepared by the method of position deposition and low-temperature drying, the process is simple, the energy consumption is low, and the cost is low. Through the composite mat...
Embodiment 1
[0064] Dissolve 1.052g of 2-methylimidazole in 80ml of methanol to obtain a 2-methylimidazole solution, dissolve 1.032g of zinc nitrate in 80ml of methanol to obtain a zinc nitrate solution, mix the 2-methylimidazole solution with the zinc nitrate solution , and stir evenly to obtain the original solution of ZIF-8;
[0065] Cut the PP melt-blown non-woven fabric to a size of 6cm*6cm;
[0066] Pour the obtained ZIF-8 original solution into a petri dish, put the PP melt-blown non-woven fabric into the petri dish, soak it in the ZIF-8 original solution, and let it stand for 96 hours;
[0067] The soaked non-woven fabric was taken out and dried at room temperature for 24 hours to obtain a ZIF-8 / non-woven fabric composite material.
Embodiment 2
[0069] Dissolve 1.052g of 2-methylimidazole in 80ml of methanol to obtain a 2-methylimidazole solution, dissolve 1.032g of zinc nitrate in 80ml of methanol to obtain a zinc nitrate solution, mix the 2-methylimidazole solution with the zinc nitrate solution , and stir evenly to obtain the original solution of ZIF-8;
[0070] Cut the PP spunbonded non-woven fabric to a size of 6cm*6cm;
[0071] Pour the obtained ZIF-8 original solution into a petri dish, put the PP melt-blown non-woven fabric into the petri dish, soak it in the ZIF-8 original solution, and let it stand for 48 hours;
[0072] The soaked non-woven fabric was taken out and dried at room temperature for 12 hours to obtain a ZIF-8 / non-woven fabric composite material.
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