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A kind of chrome-free tanning method of through type fur

A manufacturing method and a chrome-free tanning technology, which are applied in the field of chrome-free tanning of fur by pass-through type, can solve the problems that the tanning agent cannot be completely absorbed and utilized by the skin, the tanning agent and the wool of the wool are yellowed, and the production cost is increased, and the equipment can be shortened. The effect of taking up time, reducing the generation of tanning waste liquid, and improving quality

Active Publication Date: 2021-11-23
NINGXIA WUZHONG JINGYI FUR PROD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The process of tanning in the bath is a solid-liquid mass transfer process. For chrome tanning, there is a problem that the tanning agent in the bath cannot be completely absorbed by the skin. After tanning, a large amount of chrome tanning waste will be produced. These waste liquids contain chromium compounds and neutral salts, which cannot be discharged directly, which brings about the problem of chrome tanning waste liquid treatment, which not only causes environmental pressure, but also increases production costs
For organic tanning agents, the currently available organic tanning agents are mainly formaldehyde, glutaraldehyde, organic phosphine, etc., although they can solve the environmental and safety problems caused by chromium salt tanning to a certain extent, but due to the existing Fur tanning is done by immersing the whole fur in a bath. Both the quilt and the leather board will be in contact with the tanning agent. The long-term contact between the tanning agent and the wool fiber will cause certain damage to the wool fiber, or the tanning agent and the wool fiber will grow. Time interaction leads to the problem of hair yellowing, and the use of organic tanning agents still cannot avoid the problem of discharge and treatment of tanning waste

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] In the present embodiment, the chrome-free fur tanning method based on the jet technology provided by the present invention is used to tan the flea sheepskin, and the steps are as follows:

[0034] (1) Soak the pickled sheepskin obtained through the pickling treatment in a sodium bicarbonate bath, adjust the pH value of the pickled sheepskin to 4.5, and then spin water with a centrifuge until the water content of the pickled sheepskin reaches 35wt.%. about.

[0035] (2) Spread the Tan sheepskin treated in step (1) on the transmission mesh belt in a single layer in the direction of the wool side downward, and the transmission mesh belt moves at a constant speed of 0.8m / s, and the Tan sheepskin is driven horizontally by the transmission mesh belt. Under the condition of uniform movement, the tanning solution containing 30g / L glutaraldehyde is evenly sprayed from the meat surface of the Tan sheepskin to the leather plate of the Tan sheepskin through the high-pressure nozzl...

Embodiment 2

[0040] In the present embodiment, the chrome-free fur tanning method based on jet technology provided by the present invention is used to tan sheep skin, and the steps are as follows:

[0041] (1) Soak the pickled sheared sheepskin obtained through the pickling treatment (sheared sheepskin refers to the shearing of sheep wool and sheepskin specially used to manufacture sheep shearing products) in sodium formate bath, and then add it to the sodium formate bath Sodium bicarbonate is added to the solution to adjust the pH value of the pickled sheep sheared skin to 4.8, and then the centrifuge shakes water until the water content of the sheared sheep skin reaches about 28 wt.%.

[0042] (2) Lay the sheared sheepskin treated in step (1) on the conveying mesh belt in a single layer with the wool facing downward, and the conveying mesh belt moves at a constant speed of 1.2m / s, and the sheared sheep is driven by the conveying mesh belt Under the condition of uniform horizontal movemen...

Embodiment 3

[0047] In the present embodiment, the chrome-free fur tanning method based on jet technology provided by the present invention is used to tan sheep skin, and the steps are as follows:

[0048] (1) The pickled sheared sheepskin obtained through the pickling treatment is first pre-tanned with an aluminum tanning solution with an aluminum tanning agent concentration of 5g / L in a drum for about 4 hours, and then with sodium carbonate The bath liquid adjusts the pH value of the pre-tanned sheared sheepskin to 5.5, and then spins water with a centrifuge until the water content of the sheared sheepskin reaches about 35 wt.%.

[0049] (2) Lay the sheared sheepskin treated in step (1) on the transmission mesh belt in a single layer with the wool facing downward, and the transmission mesh belt moves at a constant speed of 1.5m / s, and the sheared sheep is driven by the transmission mesh belt Under the condition of uniform horizontal movement of the skin, the tanning solution containing 4...

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Abstract

The invention provides a chrome-free tanning method for through-type fur, which comprises the following steps: (1) adjusting the pH value of the pickled fur to 4.5-6.0 with lye, and then adjusting the water content of the fur; or, using an aluminum tanning agent Pre-tan the pickled fur, then use lye to adjust the pH value of the pre-tanned fur to 4.5-6.0 and adjust the moisture content of the fur; On the condition that the transmission mesh belt drives the fur to move horizontally at a uniform speed, the tanning liquid prepared by the organic tanning agent is evenly sprayed from the flesh surface of the fur to On the skin board of the fur, control the jet velocity of the tanning liquid so that the tanning liquid is evenly distributed in the skin board of the fur; (3) Pile the fur blanks obtained in step (2) for 24-48 hours to complete the tanning. The method can effectively reduce the discharge of tanning waste liquid, avoid organic tanning agents from damaging wool fibers, and improve the quality of fur.

Description

technical field [0001] The invention belongs to the technical field of fur processing and production, and relates to a chrome-free tanning method for through-type fur. Background technique [0002] At present, most fur products are tanned with basic chromium sulfate. The biggest advantage of chrome tanned leather is that the finished leather has high moisture and heat stability, which is conducive to subsequent dyeing operations. With the enhancement of consumers' health awareness, chrome-free tanned fur products will be It is the future development trend. There are two main types of machinery used in the tanning process - drums and grooves. The most commonly used is the drum, through the rotation of the drum, the tanning agent in the bath liquid can be promoted to penetrate into the leather board evenly, but the penetration of the tanning agent from the tanning liquid into the leather board is relatively slow, and the tanning time is long. In the tanning agent penetration...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C14C1/08C14C3/08C14C3/16C14C15/00
CPCC14C1/08C14C3/08C14C3/16C14C15/00
Inventor 张宗才马维宁余姗姗吴博嘉
Owner NINGXIA WUZHONG JINGYI FUR PROD
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