A polyolefin material with controllable degradation unit and high monomer utilization rate and its preparation method
A utilization rate and polyolefin technology, applied in the field of polyolefin materials, can solve problems such as wide molecular weight distribution, uncontrollable polymer molecular weight, and uneven distribution of functional groups
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[0031] The invention provides a method for preparing a degradable polyolefin with a controllable number of degradation units and a high monomer utilization rate, comprising the following steps:
[0032] The cycloketene acetal, free radical initiator and chain transfer reagent are dissolved in a solvent and then reacted with olefin or olefin derivative to obtain a degradable polyolefin material.
[0033] In the invention, firstly, the cycloketene acetal, the free radical initiator and the chain transfer reagent are dissolved in a solvent to obtain a mixed solution.
[0034] Wherein, the cycloalkene acetal is selected from one or more of 2-methylene-1,3-dioxetane, 2-methylene-1,3,6-trioxetane kind.
[0035] The free radical initiator is selected from azobisisobutyronitrile, azobisisoheptanonitrile, benzoyl peroxide, lauroyl peroxide, cumene hydroperoxide, tert-butyl hydroperoxide, dihydroperoxide tert-butyl, dicumyl peroxide, tert-butyl peroxybenzoate, tert-butyl peroxy-valera...
Embodiment 1
[0062] 0.58g 2-methylene-1,3-dioxetane, 3.2g dimethyl carbonate, 0.007g azobisisobutyronitrile and 0.02g cyanomethyl-N-methyl-N-phenyl Mix dithiocarbamate evenly, place in a 100ml stainless steel reactor, feed ethylene until the pressure reaches 3MPa, heat the mixture to 70°C under stirring, continue feeding ethylene to keep the reactor pressure constant, and react for 22 hours .
[0063] The reactor was cooled to room temperature, the crude polymerization mixture was precipitated in methanol, then centrifuged to remove the methanol, the resulting polymer was dissolved in chloroform, again precipitated in excess methanol, the methanol was removed and dried under vacuum. The degradable polyolefin 1 can be obtained.
Embodiment 2
[0065] Experiment in a method similar to Example 1, except that cyanomethyl-N-methyl-N-phenyldithiocarbamate is changed into ethoxy xanthate to obtain degradable poly Alkenes 2.
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